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In the S(N)2 reaction of cis -3- methyl...

In the `S_(N)2` reaction of cis -3- methylcyclo pentyl bromide with alkali the product formed is

A

A cis alcohol

B

A trans alcohol

C

An equimolecular mixture of cis and trans alcohol

D

There is no reaction

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The correct Answer is:
To solve the problem regarding the `S_N2` reaction of cis-3-methylcyclopentyl bromide with alkali, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of the Reactant:** - The reactant is cis-3-methylcyclopentyl bromide. - This means we have a cyclopentane ring with a bromine atom attached to one of the carbons and a methyl group at the 3rd position in a cis configuration. 2. **Draw the Structure:** - Draw the cyclopentane ring and label the carbons. - Place the bromine atom on one carbon and the methyl group on the adjacent carbon in a cis arrangement. 3. **Understand the `S_N2` Mechanism:** - The `S_N2` reaction involves a nucleophile attacking the electrophilic carbon from the opposite side of the leaving group (bromine in this case). - This results in the inversion of configuration at the carbon center where the bromine is attached. 4. **Identify the Nucleophile:** - In this case, the nucleophile is hydroxide ion (OH⁻) from the alkali (e.g., NaOH). 5. **Perform the Reaction:** - The hydroxide ion will attack the carbon that is bonded to the bromine from the backside. - As a result, the bromine will leave, and the hydroxyl group (OH) will take its place. 6. **Determine the Configuration of the Product:** - Since the original configuration is cis, the inversion during the `S_N2` reaction will lead to the formation of a trans alcohol. 7. **Identify the Product:** - The product formed will be trans-3-methylcyclopentanol. 8. **Select the Correct Option:** - Based on the options provided, the correct answer is the one that indicates the formation of a trans alcohol. ### Final Answer: The product formed in the `S_N2` reaction of cis-3-methylcyclopentyl bromide with alkali is **trans-3-methylcyclopentanol**.
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AAKASH INSTITUTE ENGLISH-HALOALKANES AND HALOARENES -Assignment (Section - B ) ( Objective Type Question(One option is correct ))
  1. How many chiral carbons are present in following structure ?

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  2. Which of the following can be used to prepare 3-bromo propene ?

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  3. In the S(N)2 reaction of cis -3- methylcyclo pentyl bromide with ...

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  4. Reaction of t-butyl bromide with sodium methoxide produces

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  5. Arrange the following in the increasing order of ease of nucleo...

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  6. Draw the structures of all the eight structural isomers that have the ...

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  7. Which one of the following compounds will give in the presence of pero...

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  8. Which of the following compounds yields only one product on monobromin...

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  9. The principle organic compound formed in the reaction is CH(...

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  10. The reactivity order of alkyl halide is 3^(@) gt 2^(@) gt 1^(@) i...

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  11. The product obtained by reduction of benzyl bromide with LIAIH(4...

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  12. Which of the following statement is incorrect ?

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  13. CH(3) OH overset(PI(3))(to) (A) overset(KCN)(to) (B) overset(H(2)O//H...

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  14. The reaction " Alcohol " +HCl hArr " Alkyl halide " +H(2)O is reve...

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  15. 3 methyl -2- pentene on reaction with HOCI gives

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  16. Among the three possible isomers of dibromo benzenes the highest ...

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  17. Benzal chloride on hydrolysis gives

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  18. For the reaction R- Br to R- O - N =O the suitable reagent is

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  19. Compound X in the reaction is

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  20. What would be the major product of the given reaction ?

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