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Each of the following reaction is giv...

Each of the following reaction is given by tertiary butylbromide except

A

`S_(N)1`

B

`S_(N)2`

C

`E_(1)`

D

`E_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, "Each of the following reactions is given by tertiary butyl bromide except," we need to analyze the behavior of tertiary butyl bromide (t-BuBr) in different types of reactions. Let's break down the steps: ### Step 1: Understand the Structure of Tertiary Butyl Bromide Tertiary butyl bromide has the structure: \[ \text{(CH}_3)_3\text{CBr} \] This means it has three methyl groups (CH₃) attached to a central carbon atom, which is also bonded to a bromine atom (Br). **Hint:** Identify the structure of the compound to understand its reactivity. ### Step 2: Identify Reaction Types Tertiary butyl bromide can undergo various types of reactions: - **SN1 Reaction**: This occurs when the leaving group (Br) departs first, forming a stable tertiary carbocation, which can then be attacked by a nucleophile. - **E1 Reaction**: Similar to SN1, but instead of a nucleophile attacking, a base abstracts a proton leading to elimination. - **E2 Reaction**: This involves a simultaneous removal of the leaving group and a proton by a base, forming a double bond. - **SN2 Reaction**: This involves a nucleophile attacking the carbon from the opposite side of the leaving group, leading to a single-step mechanism. **Hint:** Recall the characteristics of each reaction mechanism to determine which one is applicable. ### Step 3: Analyze Each Reaction 1. **SN1 Reaction**: Tertiary butyl bromide can undergo this reaction due to the formation of a stable tertiary carbocation. 2. **E1 Reaction**: Tertiary butyl bromide can also undergo this reaction since it can form a carbocation. 3. **E2 Reaction**: It can participate in this reaction as well, where a base removes a proton while the bromine leaves. 4. **SN2 Reaction**: Tertiary butyl bromide cannot undergo this reaction because the bulky groups create steric hindrance, preventing the nucleophile from effectively attacking the carbon atom. **Hint:** Compare the steric hindrance in tertiary butyl bromide to understand why SN2 is not feasible. ### Step 4: Conclusion From the analysis, we conclude that tertiary butyl bromide does not undergo the **SN2 reaction** due to steric hindrance. Therefore, the answer to the question is that the reaction that is not given by tertiary butyl bromide is the **SN2 reaction**. **Final Answer:** Tertiary butyl bromide does not undergo SN2 reaction.
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