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A compound (A) has molecular formula...

A compound (A) has molecular formula `C_(5)H_(9)CI` It does not react with bromine in `C CI_(4)` On treatment with a strong base it produces a single compound (B) (B) has a molecular formula `C_(5)H_(8)` and reacts with Baeyer's reagent . Reductive ozonotysis of (B) produces a compound (C ) which has a molecular formula `C_(5)H_(8) O_(2)`
formation of ( B) from (A) involves

A

`S_(N)2` Mechanism

B

`E_(1)` mechanism

C

`E_(2)` Mechanism

D

50% `E_(1)` and 50% `E_(2)` mechanism

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the information given about the compounds A, B, and C, and determine the mechanism involved in the formation of compound B from compound A. ### Step 1: Analyze Compound A - **Given:** Compound A has the molecular formula C₅H₉Cl. - **Hydrogen Deficiency:** To find the degree of unsaturation, we can replace Cl with CH₃ to get C₆H₁₂. The formula for an alkane is C₆H₁₄, which means there is one degree of unsaturation (1 pi bond or 1 ring). ### Step 2: Determine the Structure of Compound A - Since compound A does not react with bromine in CCl₄, it indicates that it does not contain a double bond (alkene). - Therefore, compound A must contain a ring structure (cycloalkane) with one chlorine atom. ### Step 3: Treatment with Strong Base - When compound A is treated with a strong base, it produces compound B (C₅H₈). - The reaction involves the elimination of HCl, which suggests that a hydrogen atom is removed from a beta carbon adjacent to the carbon bearing the chlorine atom. ### Step 4: Mechanism of Formation of Compound B - The formation of compound B from compound A involves an elimination reaction. - Since only one product is formed, this indicates a concerted mechanism. - The strong base abstracts a beta hydrogen, and the bond shifts to eliminate the Cl atom, leading to the formation of compound B. ### Step 5: Identify the Type of Elimination Mechanism - The elimination mechanism can be classified as either E1 or E2: - **E1 Mechanism:** Involves the formation of a carbocation intermediate. - **E2 Mechanism:** A concerted reaction where the base abstracts a hydrogen while the leaving group (Cl) departs simultaneously. - Since we are forming a single product and there is no indication of a carbocation intermediate, the mechanism must be E2. ### Conclusion The formation of compound B from compound A involves an E2 elimination mechanism. ### Final Answer The correct answer is **E2 mechanism**. ---
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