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CH(3)CH(2)NH(2) overset((CH(3)CO)(2)O)un...

`CH_(3)CH_(2)NH_(2) overset((CH_(3)CO)_(2)O)underset(Delta) to A+B`, (A) and (B) are

A

`CH_(3)CH_(2)NHCOCH_(2) + CH_(3)CH_(2)N-=C`

B

`CH_(3)CH_(2)NO_(2) + CH_(3)COOH`

C

`CH_(3)CH_(2)NHCOCH_(3)+CH_(3)COOH`

D

`CH_(3)CH_(2)NO_(2)+CH_(3)CH_(2)NHCOCH_(3)`

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AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reaction of ethylamine (CH₃CH₂NH₂) with acetic anhydride ((CH₃CO)₂O) upon heating. Let's break down the steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Ethylamine (CH₃CH₂NH₂) - Acetic anhydride ((CH₃CO)₂O) ### Step 2: Understand the Reaction Mechanism Acetic anhydride is a reactive compound that can undergo nucleophilic attack. The nitrogen atom in ethylamine has a lone pair of electrons and can act as a nucleophile. ### Step 3: Nucleophilic Attack When ethylamine is heated with acetic anhydride, the nitrogen atom attacks one of the carbonyl carbon atoms in the anhydride. This leads to the formation of a tetrahedral intermediate. ### Step 4: Formation of Products 1. The tetrahedral intermediate can collapse, leading to the formation of N-ethylacetamide (CH₃CH₂NHCOCH₃). 2. The other product formed from the acetic anhydride is acetic acid (CH₃COOH). ### Step 5: Write the Balanced Equation The overall reaction can be summarized as: \[ \text{CH}_3\text{CH}_2\text{NH}_2 + (CH_3CO)_2O \xrightarrow{\Delta} \text{CH}_3\text{CH}_2\text{NHCOCH}_3 + \text{CH}_3\text{COOH} \] ### Step 6: Identify Products A and B From the reaction, we identify: - Product A: N-ethylacetamide (CH₃CH₂NHCOCH₃) - Product B: Acetic acid (CH₃COOH) ### Conclusion Thus, the products A and B are: - A: CH₃CH₂NHCOCH₃ - B: CH₃COOH The correct answer is option C, which states that the products are N-ethylacetamide and acetic acid. ---
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AAKASH INSTITUTE ENGLISH-AMINES -Assignment Section B (Objective Type Questions) one option is correct
  1. Which of the following give para major product with aniline?

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  2. The product C is

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  3. The product is

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  4. The incorrect statement among the following is

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  5. A mixture containing primary, secondary and tertiary amine is treated ...

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  6. The compound A and B are:

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  7. CH(3)CH(2)NH(2) overset((CH(3)CO)(2)O)underset(Delta) to A+B, (A) and ...

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  8. Choose the false statement

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  9. End product of the given reaction sequence is

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  10. Among the following compounds which one will produce an enamine on rea...

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  11. An optically active compound [A] C(5)H(13)N reacts with alkaline CHCl(...

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  12. Final product of the following sequence of reactions would be

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  13. Methyl orange (an acid-base indicator) can be prepared by following se...

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  14. Consider the following sequence of reactions: [P] gives coloured ...

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  15. Many important pencilin type antibiotics possess a beta-lactum unit. W...

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  16. A nitrogenous compound (X) is treated with HNO(2), and the mixture is ...

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  17. Consider the following sequence of reaction The product [P] would...

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  18. Consider the following sequence of reactions [A](C(3)H(9)N) overset(...

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  19. Which of the following will not react with sodiumnitrite and HCl?

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  20. X is

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