Home
Class 12
CHEMISTRY
The reaction CH(3) COOH + Cl(2) overse...

The reaction
`CH_(3) COOH + Cl_(2) overset (red P) to CICH_(2) COOH + HCl` is called

A

Hell-Volhard-Zelinsky reaction

B

Birch reaction

C

Rosenmund reaction

D

Hunsdiecker reaction

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of ethanoic acid (CH₃COOH) with chlorine (Cl₂) in the presence of red phosphorus, we need to identify the name of the reaction. Here’s a step-by-step breakdown of the solution: ### Step-by-Step Solution: 1. **Identify the Reactants and Products**: - The reactants are ethanoic acid (CH₃COOH) and chlorine (Cl₂). - The products are chlorinated ethanoic acid (ClCH₂COOH) and hydrochloric acid (HCl). 2. **Understand the Role of Red Phosphorus**: - Red phosphorus acts as a catalyst in this reaction, facilitating the substitution of an alpha hydrogen atom in the carboxylic acid with a chlorine atom. 3. **Recognize the Type of Reaction**: - This reaction involves the substitution of an alpha hydrogen atom by a halogen (in this case, chlorine). This is characteristic of a specific type of reaction known as the Hell-Wolhard-Zelensky (HVZ) reaction. 4. **Confirm the Name of the Reaction**: - The Hell-Wolhard-Zelensky reaction specifically describes the halogenation of carboxylic acids at the alpha position in the presence of a halogen and red phosphorus. 5. **Eliminate Other Options**: - Other reactions mentioned (Birch reaction, Rosenmund's reaction, and Hundt-Sticker reaction) do not involve the halogenation of carboxylic acids in the same manner and can be eliminated. 6. **Conclude the Answer**: - Therefore, the reaction `CH₃COOH + Cl₂ (red P) → ClCH₂COOH + HCl` is called the **Hell-Wolhard-Zelensky reaction**. ### Final Answer: The reaction is called the **Hell-Wolhard-Zelensky reaction**. ---
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (SECTION -B OBJECTIVE TYPES QUESTIONS (ONE OPTION IS CORRECT)|24 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    AAKASH INSTITUTE ENGLISH|Exercise Assignment (SECTION -C Objective type questions more than one options are correct)|11 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    AAKASH INSTITUTE ENGLISH|Exercise Illustrations|3 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    AAKASH INSTITUTE ENGLISH|Exercise Try Yourself|5 Videos
  • AMINES

    AAKASH INSTITUTE ENGLISH|Exercise Assignment Section -J (Aakash Challengers Questions)|9 Videos

Similar Questions

Explore conceptually related problems

In the given reaction CH_(3)CH_(2) CH = CHCH_(3) overset(X) to CH_(3)CH_(2)COOH + CH_(3)COOH The X is

The reaction RCH_(2)CH_(2)COOHoverset(Red P + Br_2) to R - CH_(2) - CH(Br) -COOH

The reaction, CH_4+Cl_2 overset("hv") to , CH_3 Cl+HCl, occurs through

In the equation CH_(3)COOH+Cl_(2)+underset(-HCl)overset("red P")toA . The compound A is :

In the equation CH_(3)COOH+Cl_(2)overset("RedP")underset(-HCl)rarrA , the compound A is :

Consider the following reactions. I. CH_(2)=CHCOOH overset(Delta)to CH_(2)=CH_(2) II. III. CH_(3)CH(COOH)_(2) overset(Delta)to CH_(3)CH_(2)COOH In which cases, parent compound loses its functional group in preference?

In the reaction, Cl_(2)+CH_(4)overset(hv)toCH_(3)Cl+HCl presence of a small amount of oxygen

Which one is more acidic out of CH_(3)-COOH and CH_(3)-CH_(2)-COOH

AAKASH INSTITUTE ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -Assignment (Section A Competition Level Questions)
  1. What will be the product , when carboxy phenol, obtained by Reimer Tie...

    Text Solution

    |

  2. Which of the following aromatic acids is most acidic?

    Text Solution

    |

  3. CH(3)COOH overset (Delta) underset (P(2)O(5)) to X. Identify X

    Text Solution

    |

  4. Which one of the following orders of acidic strength is correct?

    Text Solution

    |

  5. Which of the following represents the correct order of acidity in the ...

    Text Solution

    |

  6. The correct order of acidic strength is

    Text Solution

    |

  7. Treatment of benzoic acid with Cl(2)//FeCl(3) will give

    Text Solution

    |

  8. In esterfication

    Text Solution

    |

  9. Acetyl chloride is reduced with LiAlH(4) , the product formed is

    Text Solution

    |

  10. The reaction CH(3) COOH + Cl(2) overset (red P) to CICH(2) COOH + HC...

    Text Solution

    |

  11. Saponification of ethyl benzoate with caustic soda as alkali gives

    Text Solution

    |

  12. Which of the following acids has the smallest dissociation constant?

    Text Solution

    |

  13. Which of the following compounds will show the maximum ‘enol’ content?

    Text Solution

    |

  14. Aliphatic aldehyde can be oxidised by

    Text Solution

    |

  15. Formaldehyde when treated with KOH (caustic potash) gives methanol and...

    Text Solution

    |

  16. Reactions

    Text Solution

    |

  17. Bakelite is prepared by the reaction between

    Text Solution

    |

  18. Fehling test is positive for

    Text Solution

    |

  19. 2C(6)H(5)CHO overset(NaOH) to C(6)H(5)CH(2)OH + C(6)H(5)COONa The si...

    Text Solution

    |

  20. Text Solution

    |