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An organic compound [X]. C(5)H(8)O react...

An organic compound [X]. `C_(5)H_(8)O` reacts with hydroxylamine to form [Y]. In the presence of conc. `H_(2)SO_(4)` gives `delta`-lactam. [X] neither give Benedicts test nor it respond positively towards haloform test. The compound [X] is

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The correct Answer is:
To solve the problem, we need to identify the organic compound [X] with the molecular formula \( C_5H_8O \) based on the given reactions and tests. Let's break it down step by step. ### Step 1: Analyze the Molecular Formula The compound [X] has the molecular formula \( C_5H_8O \). This indicates that it could be an unsaturated compound, possibly an aldehyde or ketone due to the presence of a carbonyl group (C=O). **Hint:** The degree of unsaturation can be calculated using the formula: \( \text{Degree of Unsaturation} = \frac{(2C + 2 - H)}{2} \). ### Step 2: Reactivity with Hydroxylamine The problem states that [X] reacts with hydroxylamine (NH2OH) to form [Y]. This indicates that [X] contains a carbonyl group (either an aldehyde or a ketone) since hydroxylamine forms oximes with carbonyl compounds. **Hint:** Hydroxylamine reacts with carbonyl compounds to form oximes, which are characterized by the functional group -C=N-OH. ### Step 3: Formation of Delta-Lactam In the presence of concentrated sulfuric acid (H2SO4), [X] gives a delta-lactam. A lactam is a cyclic amide, and a delta-lactam specifically refers to a lactam where the nitrogen atom is four carbons away from the carbonyl carbon. **Hint:** A delta-lactam can be formed from a compound that has a suitable structure to allow for cyclization, typically involving a carbonyl group and an amine. ### Step 4: Tests for Aldehyde and Ketone The compound [X] does not give a positive Benedict's test, which means it is not an aldehyde that can be oxidized to a carboxylic acid. Additionally, it does not respond positively to the haloform test, indicating that it is not a methyl ketone (which would have a structure like CH3CO-). **Hint:** The absence of a positive haloform test suggests that there is no methyl ketone structure (CH3CO-) present in [X]. ### Step 5: Identify Possible Structures Given the molecular formula \( C_5H_8O \) and the information from the tests, we can deduce that [X] is likely a cyclic compound since it can form a lactam. The options provided in the question likely include cyclopentanone or cyclobutanone derivatives. **Hint:** Consider the structure of cyclopentanone and cyclobutanone to see which one fits the criteria of not giving the tests mentioned. ### Step 6: Conclusion After analyzing the possible structures, we find that cyclopentanone (which has a carbonyl group but does not fit the criteria for the tests mentioned) is the most plausible candidate for [X]. Thus, the compound [X] is **cyclopentanone**. ### Final Answer The compound [X] is **cyclopentanone**. ---
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AAKASH INSTITUTE ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS -Assignment (SECTION -B OBJECTIVE TYPES QUESTIONS (ONE OPTION IS CORRECT)
  1. Consider the following sequence of reactions: The final product [...

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  2. Consider the following sequence of reaction The final product [B]...

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  3. CH(3)-overset(O)overset(||)C-CH(3)overset("Conc")underset(HNO(3))to Pr...

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  5. The appropriate reagent for the transformation :

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  7. The product predominates is

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  8. Which of the following carbonyl oxygen will form strongest hydrogen bo...

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  9. Which of the following would be the best synthesis of benzoic acid fro...

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  10. Consider the following sequence of reactions: Major product [B] o...

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  11. The compound which is not reduced by LiAIH(4) is

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  12. Consider the following sequence of reactions. The product [A] and...

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  13. The compound can be compounded oxidized into

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  14. Which of the following conversion is known as Stefen's reduction?

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  15. Which reagent or sequence of reagents would best accomplish the follow...

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  16. An organic compound [X]. C(5)H(8)O reacts with hydroxylamine to form [...

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  17. Alanine can be obtained from acetaldehyde by the following sequence of...

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  18. Which of the following carboxylic acid ismost reluctant to form ester ...

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  19. Among the given compounds

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  20. A is

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