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In Arrhenius equation , K=Ae^(-Ea//RT) ....

In Arrhenius equation , `K=Ae^(-E_a//RT)` . The A is

A

Activation energy

B

Enthalpy of reaction

C

Free energy of reaction

D

Rate constant of the reaction at infinite temperature

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The correct Answer is:
To answer the question regarding the Arrhenius equation \( K = A e^{-\frac{E_a}{RT}} \), we need to identify what the variable \( A \) represents. ### Step-by-Step Solution: 1. **Understanding the Arrhenius Equation**: The Arrhenius equation describes how the rate constant \( K \) of a chemical reaction depends on temperature \( T \) and activation energy \( E_a \). The equation is given by: \[ K = A e^{-\frac{E_a}{RT}} \] where: - \( K \) = rate constant - \( A \) = pre-exponential factor (also known as the Arrhenius factor or frequency factor) - \( E_a \) = activation energy - \( R \) = gas constant - \( T \) = temperature in Kelvin 2. **Identifying \( A \)**: In the context of the Arrhenius equation, \( A \) is not the activation energy, enthalpy of the reaction, or free energy of the reaction. Instead, it is a constant that provides a measure of the frequency of collisions and the orientation of reactants in a reaction. 3. **Behavior at Infinite Temperature**: When the temperature \( T \) approaches infinity, the term \( -\frac{E_a}{RT} \) approaches zero, making the exponential term \( e^{0} = 1 \). Thus, at infinite temperature: \[ K = A \cdot 1 = A \] This implies that \( A \) can be considered as the rate constant \( K \) at infinite temperature. 4. **Conclusion**: Therefore, in the Arrhenius equation, \( A \) is known as the **pre-exponential factor** or **frequency factor**, and it can also be interpreted as the rate constant at infinite temperature. ### Final Answer: In the Arrhenius equation, \( A \) is the **pre-exponential factor** or **frequency factor**, which can also be interpreted as the rate constant at infinite temperature.
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