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For a reaction of type aA+bBrarr"pro...

For a reaction of type
`aA+bBrarr"products", (-d[A])/(dt)` is equal to

A

`(-d[B])/(dt)`

B

`-b/d(d[B])/(dt)`

C

`-a/(b)xx(d[B])/(dt)`

D

`-b/(a)xx(d[B])/(dt)`

Text Solution

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The correct Answer is:
To solve the problem, we need to express the rate of change of concentration of reactant A in terms of the rate of change of concentration of reactant B. The reaction is given as: \[ aA + bB \rightarrow \text{products} \] ### Step-by-Step Solution: 1. **Write the Rate Expression**: The rate of the reaction can be expressed in terms of the change in concentration of A and B. The rate of disappearance of A can be written as: \[ -\frac{d[A]}{dt} = \frac{1}{a} \frac{d[A]}{dt} \] Similarly, for B, it can be expressed as: \[ -\frac{d[B]}{dt} = \frac{1}{b} \frac{d[B]}{dt} \] 2. **Relate the Rates**: From the stoichiometry of the reaction, we can relate the rates of change of A and B: \[ -\frac{1}{a} \frac{d[A]}{dt} = -\frac{1}{b} \frac{d[B]}{dt} \] 3. **Rearranging the Equation**: Rearranging the above equation gives us: \[ \frac{d[A]}{dt} = -\frac{a}{b} \frac{d[B]}{dt} \] 4. **Final Expression**: Thus, we can express the rate of change of concentration of A as: \[ -\frac{d[A]}{dt} = \frac{a}{b} \frac{d[B]}{dt} \] 5. **Conclusion**: Therefore, the expression for \(-\frac{d[A]}{dt}\) in terms of \(-\frac{d[B]}{dt}\) is: \[ -\frac{d[A]}{dt} = -\frac{a}{b} \frac{d[B]}{dt} \]
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AAKASH INSTITUTE ENGLISH-CHEMICAL KINETICS-ASSIGNMENT (SECTION A : Objective Type Questions)
  1. The unit of rate and rate constant are same for a

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  2. For a reaction of type aA+bBrarr"products", (-d[A])/(dt) is equal ...

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  3. For a gaseous reaction, the rate of reaction may be expressed in the u...

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  4. A gaseous reaction A(2)(g) rarr B(g) + (1)/(2) C(g) shows increase in ...

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  5. Which of the following will react at the highest rate ?

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  6. Which of the following does not affect the rate of reaction?

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  7. In a reaction 2X+Y rarrX(2),Y the reactant X will disappear at

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  8. During the course of a chemical reaction , the rate constant .

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  9. A reaction involving two different reactants can never be:

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  10. For the hypothetical reaction 2A rarr3C , the reaction rate r in term...

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  11. In the reaction , A+2Bto6C+2D, if the initial rate -(d[A])/(dt) at t= ...

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  12. For the reaction N(2) + 3 H(2) to 2 NH(3) The rate of change of conc...

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  13. The graph plotted between concentration versus time

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  14. For reaction, 2B+A rarr 2C Which of the following is correct ?

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  15. For the homogeneous elementary reaction, A+B rarrC, the unit of rate ...

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  16. The rate law for a reaction between A and B is given by rate = k[A]^(n...

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  17. Consider the reaction, 2A + B rarr C + D , If the rate expression is...

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  18. The rate constant is numerically the same for three reaction of first ...

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  19. Assuring an elementary reaction H2O2+3I^(-)+2H^(+)rarr2H2O+I3^(-) . Th...

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  20. For a reaction A+B rarr products, the rate of reaction was doubled whe...

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