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For reaction, 2B+A rarr 2C Which of th...

For reaction, `2B+A rarr 2C`
Which of the following is correct ?

A

Rate of disappearance of B is twice that of rate of disappearance of C

B

Rate of disappearance of A is twice that of rate of disappearance of C

C

Rate of appearance of C is twice that of rate of disappearance of A

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction \(2B + A \rightarrow 2C\), we need to analyze the rates of disappearance and appearance of the reactants and products involved in the reaction. ### Step-by-Step Solution: 1. **Write the Rate Expression**: For the reaction \(2B + A \rightarrow 2C\), we can express the rate of the reaction in terms of the change in concentration of the reactants and products: \[ \text{Rate} = -\frac{1}{2} \frac{d[B]}{dt} = -\frac{d[A]}{dt} = \frac{1}{2} \frac{d[C]}{dt} \] 2. **Analyze the Rate of Disappearance of B**: From the rate expression, we can see that the rate of disappearance of \(B\) is: \[ -\frac{d[B]}{dt} = 2 \cdot \frac{d[C]}{dt} \] This means that the rate of disappearance of \(B\) is equal to the rate of appearance of \(C\), but it is not twice the rate of \(C\). 3. **Analyze the Rate of Disappearance of A**: The rate of disappearance of \(A\) is: \[ -\frac{d[A]}{dt} = \frac{d[C]}{dt} \] This indicates that the rate of disappearance of \(A\) is equal to half the rate of appearance of \(C\). 4. **Analyze the Rate of Appearance of C**: The rate of appearance of \(C\) can be expressed as: \[ \frac{d[C]}{dt} = 2 \cdot \left(-\frac{d[A]}{dt}\right) \] This means that the rate of appearance of \(C\) is twice the rate of disappearance of \(A\). 5. **Conclusion**: Based on the analysis: - The rate of disappearance of \(B\) is equal to the rate of appearance of \(C\). - The rate of disappearance of \(A\) is half the rate of appearance of \(C\). - The rate of appearance of \(C\) is twice the rate of disappearance of \(A\). Therefore, the correct statement among the options provided is that the rate of appearance of \(C\) is twice the rate of disappearance of \(A\). ### Final Answer: The correct option is that the rate of appearance of \(C\) is twice the rate of disappearance of \(A\). ---
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AAKASH INSTITUTE ENGLISH-CHEMICAL KINETICS-ASSIGNMENT (SECTION A : Objective Type Questions)
  1. For the reaction N(2) + 3 H(2) to 2 NH(3) The rate of change of conc...

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  2. The graph plotted between concentration versus time

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  3. For reaction, 2B+A rarr 2C Which of the following is correct ?

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  4. For the homogeneous elementary reaction, A+B rarrC, the unit of rate ...

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  5. The rate law for a reaction between A and B is given by rate = k[A]^(n...

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  6. Consider the reaction, 2A + B rarr C + D , If the rate expression is...

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  7. The rate constant is numerically the same for three reaction of first ...

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  8. Assuring an elementary reaction H2O2+3I^(-)+2H^(+)rarr2H2O+I3^(-) . Th...

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  9. For a reaction A+B rarr products, the rate of reaction was doubled whe...

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  10. The overall order of reaction between X & Y is 3. Which of the followi...

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  11. For a zero order reaction, K=1xx10^(-3)"mol L"^(-1)s^(-1) If initi...

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  12. Which of the following statement is not correct ?

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  13. Consider the following in respect of zero order reaction. I. t(1//2)...

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  14. If initial concentration is reduced to 1//4^(th) in a zero order react...

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  15. If initial concentration is doubled, the time for half reaction is als...

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  16. The inversion of cane sugar is represented by C(12)H(22)O(11) + H(2)...

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  17. For a lst order reaction , a straight line is obtained if you plot

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  18. Which order reaction obeys the expression t(1//2)prop1[A] ?

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  19. The graph of t(1//2) versus initial concentration 'a' is for

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  20. Reactant 'A' (initial concentration, a) reacts according to zero order...

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