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High purity dihydrogen is obtained by el...

High purity dihydrogen is obtained by electrolysing

A

Warm aqueous barium hydroxide

B

Brine solution

C

Acidified sulphate solution

D

Water gas

Text Solution

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The correct Answer is:
To determine the correct option for obtaining high purity dihydrogen through electrolysis, we can analyze each option provided in the question. ### Step-by-Step Solution: 1. **Understanding Electrolysis**: - Electrolysis is a process that uses electrical energy to drive a non-spontaneous chemical reaction. In the case of water, it involves the decomposition of water into hydrogen and oxygen gases. 2. **Evaluating the Options**: - **Option 1: Warm Aqueous Barium Hydroxide**: - Barium hydroxide is a strong base and acts as an excellent electrolyte. When electrolyzed, it produces high purity hydrogen gas (around 99.95% purity). This is because it provides a good medium for the conduction of electricity. - **Option 2: Brine Solution**: - Brine (saltwater) can also conduct electricity but typically produces chlorine gas at the anode and hydrogen gas at the cathode. The presence of chlorine can contaminate the hydrogen produced, leading to lower purity. - **Option 3: Acidified Sulfate Solution**: - Acidified sulfate solutions can produce hydrogen gas, but the purity may not be as high as that obtained from barium hydroxide due to possible side reactions and impurities. - **Option 4: Water Gas**: - Water gas is a mixture of hydrogen and carbon monoxide. Electrolysis of water gas would not yield pure hydrogen, as it contains carbon monoxide, which is an impurity. 3. **Conclusion**: - Based on the analysis, the best option for obtaining high purity dihydrogen is **Option 1: Warm Aqueous Barium Hydroxide**. This method yields hydrogen gas with a purity greater than 99.95%. ### Final Answer: **High purity dihydrogen is obtained by electrolyzing warm aqueous barium hydroxide.** ---
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