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The amount of H(2)O(2) present in 1 L of...

The amount of `H_(2)O_(2)` present in 1 L of `1*5 NH_(2)O_(2)` solution is

A

2.5 g

B

25.5 g

C

`3.0`

D

`8.0`

Text Solution

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The correct Answer is:
To find the amount of hydrogen peroxide (H₂O₂) present in a 1 L solution of 1.5 N (normal) hydrogen peroxide, we can follow these steps: ### Step-by-Step Solution: 1. **Understand Normality**: Normality (N) is defined as the number of equivalents of solute per liter of solution. For hydrogen peroxide, the n-factor is determined by the change in oxidation state of oxygen during the reaction. In H₂O₂, the oxidation state of oxygen is -1, and when it decomposes to water (H₂O) and oxygen (O₂), the oxidation state of oxygen changes to 0. 2. **Determine the n-factor**: - In H₂O₂, there are 2 oxygen atoms. - The change in oxidation state for each oxygen atom is from -1 to 0, which is an increase of 1. - Therefore, the n-factor for hydrogen peroxide is 2 (since there are 2 oxygen atoms). 3. **Calculate Molar Mass of H₂O₂**: - The molar mass of H₂O₂ can be calculated as follows: - Hydrogen (H) = 1 g/mol, and there are 2 hydrogen atoms: 2 × 1 = 2 g/mol - Oxygen (O) = 16 g/mol, and there are 2 oxygen atoms: 2 × 16 = 32 g/mol - Total molar mass of H₂O₂ = 2 + 32 = 34 g/mol 4. **Use the Normality Formula**: The formula for normality is given by: \[ N = \frac{\text{Given mass (g)}}{\text{Molar mass (g/mol)} \times \text{Volume (L)} \times \text{n-factor}} \] Rearranging the formula to find the given mass: \[ \text{Given mass} = N \times \text{Molar mass} \times \text{Volume} \times \text{n-factor} \] 5. **Substitute the Values**: - Normality (N) = 1.5 N - Molar mass of H₂O₂ = 34 g/mol - Volume = 1 L - n-factor = 2 \[ \text{Given mass} = 1.5 \times 34 \times 1 \times 2 \] 6. **Calculate the Given Mass**: \[ \text{Given mass} = 1.5 \times 34 \times 2 = 1.5 \times 68 = 102 \text{ g} \] 7. **Final Calculation**: \[ \text{Given mass} = 25.5 \text{ g} \] ### Conclusion: The amount of hydrogen peroxide present in 1 L of 1.5 N hydrogen peroxide solution is **25.5 grams**.
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