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H(2)O and H(2)O(2) resemble in...

`H_(2)O and H_(2)O_(2)` resemble in

A

Hybridisation of oxygen

B

Oxidation state of oxygen

C

Structure

D

Bond angle

Text Solution

AI Generated Solution

The correct Answer is:
To determine how \( H_2O \) (water) and \( H_2O_2 \) (hydrogen peroxide) resemble, we will analyze the given options step by step. ### Step 1: Draw the Structures 1. **Water (\( H_2O \))**: The structure of water is bent or V-shaped due to the two lone pairs of electrons on the oxygen atom. 2. **Hydrogen Peroxide (\( H_2O_2 \))**: The structure of hydrogen peroxide is an open book structure, where each oxygen is bonded to another oxygen and a hydrogen atom. Each oxygen also has two lone pairs. ### Step 2: Analyze Hybridization - **Water (\( H_2O \))**: - Oxygen forms 2 bonds (with hydrogen) and has 2 lone pairs. - The steric number (number of bond pairs + number of lone pairs) is \( 2 + 2 = 4 \). - Therefore, the hybridization of oxygen in water is \( sp^3 \). - **Hydrogen Peroxide (\( H_2O_2 \))**: - Each oxygen forms 2 bonds (one with hydrogen and one with another oxygen) and has 2 lone pairs. - The steric number is also \( 2 + 2 = 4 \). - Thus, the hybridization of oxygen in hydrogen peroxide is also \( sp^3 \). ### Conclusion for Hybridization Both \( H_2O \) and \( H_2O_2 \) have oxygen atoms that are \( sp^3 \) hybridized. Therefore, the first option is correct. ### Step 3: Analyze Oxidation State - **Water (\( H_2O \))**: - The oxidation state of oxygen is \( -2 \) because it forms two bonds with hydrogen. - **Hydrogen Peroxide (\( H_2O_2 \))**: - The oxidation state of oxygen is \( -1 \) because each oxygen is bonded to another oxygen and one hydrogen. ### Conclusion for Oxidation State The oxidation states of oxygen in \( H_2O \) and \( H_2O_2 \) are different. Thus, the second option is incorrect. ### Step 4: Analyze Structure - The structure of water is bent (V-shaped), while the structure of hydrogen peroxide is an open book shape. ### Conclusion for Structure Since the structures are different, the third option is incorrect. ### Step 5: Analyze Bond Angles - **Water (\( H_2O \))**: The bond angle is approximately \( 104.5^\circ \). - **Hydrogen Peroxide (\( H_2O_2 \))**: The bond angle is around \( 101.9^\circ \). ### Conclusion for Bond Angles The bond angles are different, so the fourth option is also incorrect. ### Final Answer The correct resemblance between \( H_2O \) and \( H_2O_2 \) is that **both have \( sp^3 \) hybridized oxygen atoms**.
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