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How many isomeric halogen derivatives in...

How many isomeric halogen derivatives including stereoisomers are possible for `C_(2)H_(2)Br_(2)` ?

A

2

B

3

C

4

D

5

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of isomeric halogen derivatives, including stereoisomers, for the compound \( C_2H_2Br_2 \), we can follow these steps: ### Step 1: Identify the Structure The molecular formula \( C_2H_2Br_2 \) suggests that the compound has two carbon atoms, two hydrogen atoms, and two bromine atoms. Given that there are two carbon atoms, we can assume that there is a double bond between them, similar to ethene (\( C_2H_4 \)). **Hint:** Consider the general structure of alkenes when dealing with \( C_2H_2Br_2 \). ### Step 2: Draw the Basic Structure The basic structure can be represented as follows: \[ C=C \] With two bromine atoms and two hydrogen atoms to be arranged around the double bond. **Hint:** Visualize the double bond and how substituents can be arranged around it. ### Step 3: Identify Possible Isomers 1. **Identify the first isomer**: Both bromine atoms can be on one carbon atom, and both hydrogen atoms on the other carbon atom: - Structure: \( Br-Br \) on one carbon and \( H-H \) on the other carbon. 2. **Identify the second isomer (Cis)**: Both bromine atoms can be on the same side of the double bond: - Structure: \( C=C \) with \( Br \) and \( Br \) on one side and \( H \) and \( H \) on the other side (cis configuration). 3. **Identify the third isomer (Trans)**: The bromine atoms can be on opposite sides of the double bond: - Structure: \( C=C \) with \( Br \) on one carbon and \( H \) on the other carbon, and vice versa (trans configuration). **Hint:** Remember that the presence of a double bond allows for cis and trans isomerism. ### Step 4: Count the Isomers - The first isomer is the one with both bromines on one carbon and both hydrogens on the other. - The second isomer is the cis isomer. - The third isomer is the trans isomer. Thus, we have three distinct isomers: 1. \( Br-Br \) on one carbon, \( H-H \) on the other. 2. Cis isomer. 3. Trans isomer. **Hint:** Ensure that you do not double count any isomers that are identical in structure. ### Conclusion In total, there are **3 isomeric halogen derivatives**, including stereoisomers, for \( C_2H_2Br_2 \). **Final Answer:** The correct option is **B (3)**.
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AAKASH INSTITUTE ENGLISH-HALOALKANES AND HALOARENES -EXERCISE
  1. Which of the following is an example of aryl alkyl halide ?

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  2. Which of the following alkyl halides is iso -butyl bromide ?

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  3. How many isomeric halogen derivatives including stereoisomers are poss...

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  4. Hunsdiecker reaction is used to prepare alkyl chloride and alkyl bromi...

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  5. The best reagent for converting an alcohol into the corrosponding chlo...

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  6. Iso -butylene can be converted into tert -butyl bromide by its reactio...

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  7. The number of isomers possible for the molecular formula C(2) FCIBrl i...

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  8. Which of the following will react most readily with HI ?

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  9. The isomer of C(6)H(14) which will give maximum number of monochlorode...

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  10. Which of the following is most reactive towards electrophillic aromat...

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  11. Amongst the C-X bond the correct bond energy order is

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  12. Which of the following has highest boilling point ?

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  13. Out of the following compounds which one will have zero dipole moment ...

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  14. Treatment of ammonia with excess of ethyl chloride will yield

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  15. Identity Z in the following sequence

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  16. Most reactive halide towards S(N^(1)) reactions is

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  17. Which of the following is the most reactive towards nucleophilic subst...

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  18. NBS is a specific reagent for

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  19. For the reaction C(2)H(5) OH + HX to C2 H(5) X + H(2)O , the order of ...

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  20. Which of the following is not true for S(N^(1)) reaction ?

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