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Which of the following is an example of ...

Which of the following is an example of 1,2 -elimination ?

A

`CH_(3)-underset(Br)underset(|)(CH)-CH_(3) overset("Reagent")(rarr)CH_(4)-CH=CH_(2)`

B

C

`H_(2)underset(X)underset(|)(C)-CH_(2)-CH_(2)-underset(Y)underset(|)(CH_(2))overset("Reagent")(rarr)H_(3)C-CH=CH-CH_(3)`

D

All of these

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The correct Answer is:
To determine which of the given reactions is an example of 1,2-elimination, we need to analyze each option based on the definition of 1,2-elimination. This type of elimination involves the removal of atoms or groups from adjacent carbon atoms. ### Step-by-Step Solution: 1. **Understanding 1,2-elimination**: - 1,2-elimination, also known as alpha-beta elimination, involves the removal of atoms or groups from two adjacent carbon atoms in a molecule. 2. **Analyzing Option A**: - The reaction given is CH3CHBrCH3 in the presence of a reagent, resulting in an alkene. - Here, bromine (Br) is eliminated from the second carbon, and a hydrogen (H) is eliminated from the first carbon. - Since the elimination occurs from two adjacent carbons (1 and 2), this reaction is indeed a 1,2-elimination. 3. **Analyzing Option B**: - The reactant is CH2-X CH2-CH2-Y, which leads to the formation of a three-membered ring. - In this case, X is eliminated from the first carbon and Y from the third carbon. - Since the elimination occurs from non-adjacent carbons (1 and 3), this is a 1,3-elimination, not a 1,2-elimination. 4. **Analyzing Option C**: - The reactant is CH2X CH2CH2CH2Y, which also leads to the formation of an alkene. - Here, X is eliminated from the first carbon and Y from the fourth carbon. - This results in a 1,4-elimination, as the elimination occurs from carbons that are not adjacent. 5. **Conclusion**: - Based on the analysis, only Option A demonstrates 1,2-elimination, while Options B and C do not. ### Final Answer: - The correct answer is **Option A**, which is an example of 1,2-elimination.
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AAKASH INSTITUTE ENGLISH-HALOALKANES AND HALOARENES -EXERCISE
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  2. Which of the following does not form Grignard reagent on reaction with...

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  3. 1-phenyl-2-chloropropane on treating with alc. KOH gives mainly

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  4. An alkyl halide on reaction with sodium in the presence of ether gives...

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  5. Ethyl bromide reacts with lead sodium alloy to form:

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  6. Allybromide on dehydrobromination gives

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  7. Identify the major product

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  8. Identify the most suitable reagent for the following conversion ? C...

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  9. Which of the following is an example of 1,2 -elimination ?

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  10. What is the general formula for an aliphatic alcohol? (R=alkyl group)

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  11. IUPAC name of Gammexene is

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  12. Pyrene is trade name of when used as fire extinguisher

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  13. Which of the following with aqueous KOH will give acetaldehyde ?

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  14. Carbylamine test is performed in alcoholic KOH by heating a mixture of...

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  15. What happens when C Cl(4) is treated with AgNO(3) solution ?

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  16. DDT is formed from

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  17. Iodoform in medicines is used as

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  18. What happens when chloroform is exposed to air in presence of sunl...

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  19. Non - sticking frying pans are coated with teflon which is polymer of

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  20. Which of the following are arranged in the decreasing order of dipole ...

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