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CD(2) = CH - CH(2) - Br is subjected to ...

`CD_(2)` = CH - `CH_(2) - `Br is subjected to `S_(N)1 and S_(N)`2 reactions separately, which of the following statement is correct ?

A

both `S_(N)1 and S_(N)`2 give two products

B

Both `S_(N)1 and S_(N)2` give only product

C

`S_(N)1` gives two products but `S_(N)`2 gives only one product

D

`S_(N)1`gives one product but `S_(N)`2 gives two products

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AI Generated Solution

The correct Answer is:
To solve the problem regarding the reactions of CD₂=CH-CH₂-Br with SN1 and SN2 mechanisms, let's break it down step by step. ### Step-by-Step Solution: 1. **Identify the Reaction Mechanisms**: - **SN1 Mechanism**: This is a two-step process where the first step involves the formation of a carbocation after the leaving group (Br) departs. The second step involves the nucleophile attacking the carbocation. - **SN2 Mechanism**: This is a one-step process where the nucleophile attacks the carbon atom simultaneously as the leaving group (Br) departs. 2. **Analyze the Structure**: - The compound is CD₂=CH-CH₂-Br. The bromine (Br) is the leaving group. - The carbon atom bonded to Br is a secondary carbon, which can stabilize a carbocation. 3. **SN2 Reaction**: - In an SN2 reaction, the nucleophile will attack the carbon atom bonded to Br, leading to the simultaneous departure of Br. - This results in the formation of one product: CD₂-CH(CH₂)-Br (where the nucleophile replaces Br). 4. **SN1 Reaction**: - In an SN1 reaction, the first step is the departure of Br, forming a carbocation (CD₂=CH-CH₂⁺). - The carbocation can be stabilized by resonance with the adjacent double bond. - The nucleophile can attack the carbocation from either side, leading to two possible products: - If the nucleophile attacks from the front, the product is CD₂-CH(CH₂)-Br. - If the nucleophile attacks from the back, the product is CD₂Br-CH-CH₂. - This results in a racemic mixture of products. 5. **Conclusion**: - In the SN2 mechanism, only one product is formed. - In the SN1 mechanism, two products are formed due to the possibility of attack from both sides of the planar carbocation. ### Final Answer: - The correct statement is: In SN1, two products are formed, while in SN2, one product is formed.
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