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When CH(3)CH(2)CHCl(2) is treated with "...

When `CH_(3)CH_(2)CHCl_(2)` is treated with `"NaNH"_(2)` the product formed is:

A

`CH_(3) - CH = CH_(2)`

B

`CH_(3) - C equiv CH`

C

D

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The correct Answer is:
To solve the problem of what product is formed when `CH3CH2CHCl2` is treated with `NaNH2`, we can follow these steps: ### Step 1: Identify the Reactants The reactant is `CH3CH2CHCl2`, which is 1,1-dichloropropane. The reagent is sodium amide (`NaNH2`), a strong base. **Hint:** Recognize the structure of the reactant and the nature of the reagent. ### Step 2: Understand the Reaction Mechanism `NaNH2` is a strong base that can deprotonate hydrogen atoms and eliminate halides. In this case, it will first remove one of the chlorine atoms and a hydrogen atom from the carbon chain. **Hint:** Remember that strong bases can lead to elimination reactions, resulting in the formation of alkenes or alkynes. ### Step 3: First Elimination When `NaNH2` reacts with `CH3CH2CHCl2`, it can remove one `Cl` atom and one `H` atom from the adjacent carbon, leading to the formation of a double bond. The first step results in the formation of `CH3CH=CHCl` (propene with a chlorine substituent). **Hint:** Look for the formation of a double bond after the elimination of HCl. ### Step 4: Second Elimination The product `CH3CH=CHCl` can further react with `NaNH2`. The strong base can again remove the remaining `Cl` and a hydrogen atom adjacent to it, leading to the formation of a triple bond. This results in the final product `CH3C≡CH` (propyne). **Hint:** Consider the possibility of multiple elimination reactions when a strong base is involved. ### Step 5: Final Product The final product after both eliminations is `CH3C≡CH`, which is propyne. **Hint:** Ensure that you account for all the halides and hydrogens that are removed during the reaction. ### Conclusion When `CH3CH2CHCl2` is treated with `NaNH2`, the final product formed is `CH3C≡CH` (propyne). **Final Answer:** The product formed is `CH3C≡CH` (option B).
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