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In Friedel-Crafts acylation, besides AlC...

In Friedel-Crafts acylation, besides `AlCl_(3)`, the other reactants are

A

`C_(6)H_(6) + CH_(3)Cl`

B

`C_(6)H_(6) + CH_(4)`

C

`C_(6)H_(6) + NH_(2)-NH_(2)`

D

`C_(6)H_(6) + CH_(3)COCl`

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The correct Answer is:
To solve the question regarding the reactants used in Friedel-Crafts acylation, we can break down the process step by step: ### Step 1: Identify the Reaction Friedel-Crafts acylation is a reaction that introduces an acyl group into an aromatic ring. The general formula for the acylation reaction can be represented as: \[ \text{Benzene} + \text{Acyl Chloride} \xrightarrow{\text{AlCl}_3} \text{Acylated Product} + \text{HCl} \] ### Step 2: Identify the Reactants In Friedel-Crafts acylation, the key reactants are: 1. **Benzene (C₆H₆)** - This is the aromatic compound that will undergo acylation. 2. **Acyl Chloride** - The most common acyl chloride used is **acetyl chloride (CH₃C(O)Cl)**. 3. **Lewis Acid Catalyst** - The catalyst used is **Aluminum Chloride (AlCl₃)**, which facilitates the generation of the electrophile. ### Step 3: Write the Reaction The reaction can be summarized as follows: \[ \text{C}_6\text{H}_6 + \text{CH}_3\text{C(O)Cl} \xrightarrow{\text{AlCl}_3} \text{C}_6\text{H}_5\text{C(O)CH}_3 + \text{HCl} \] Here, the product formed is **acetophenone (C₆H₅C(O)CH₃)**. ### Step 4: Conclusion Thus, besides **AlCl₃**, the other reactants in Friedel-Crafts acylation are: - **Benzene (C₆H₆)** - **Acetyl Chloride (CH₃C(O)Cl)** ### Final Answer The reactants used in Friedel-Crafts acylation, besides AlCl₃, are benzene (C₆H₆) and acetyl chloride (CH₃C(O)Cl). ---
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AAKASH INSTITUTE ENGLISH-HYDROCARBONS-Assignment(Section - C) (Previous Years Questions)
  1. Which of the following statements is not compatible with arenes?

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  2. When acetylene is passed through dil. H(2)SO(4) in the presence of HgS...

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  3. In Friedel-Crafts acylation, besides AlCl(3), the other reactants are

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  4. Gammaexane is

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  5. In Friedal craft reaction Toluene can be prepared by:

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  6. 2-butene shows geometrical isomerism due to:

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  7. Dihedral angle in staggerred form of ethane is

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  8. Which alkene on ozonolysis gives CH(3)CH(2)CHO and CH(3)underset(O)und...

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  9. Products of the following reaction : CH(3)C-=C CH(2)CH(3) underset(...

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  10. Which of the compounds with molecular formula C(5)H(10) yields aceton...

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  11. Anti-Markownikoff's addition of HBr is not observed in

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  12. Given I and II are

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  13. Which of the following conformers for ethylene glycol is most stable ?

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  14. Reaction of HBr with propene in the presence of peroxide gives :-

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  15. Which one of the following is a free-radical substitution reaction :

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  16. Using anhydrous AlCl3 as catalyst, which one of the following reaction...

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  17. Which of the following compounds undergoes nucleophilic substitution r...

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  18. Which will undergo fastest S(N)2 substitution reaction when treated wi...

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  19. Y in the reaction is

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  20. How many chiral compounds are possible on monochlorination of 2-methyl...

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