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Two flasks A and B of equal capacity of ...

Two flasks A and B of equal capacity of volume contain `SO_3` and CO gas respectively under similar conditions of temperature and pressure. Then, which of the following statement is true?

A

A has twice the number of moles as that of B

B

B has twice the number of moles as that of A

C

A and B have equal number of moles

D

B has twice the number of atoms as that of A

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The correct Answer is:
To solve the problem, we need to analyze the information provided about the two flasks A and B containing different gases under the same conditions of temperature and pressure. ### Step-by-Step Solution: 1. **Identify the Gases and Their Conditions**: - Flask A contains sulfur trioxide (SO₃). - Flask B contains carbon monoxide (CO). - Both flasks have equal volume and are under the same temperature and pressure conditions. 2. **Apply the Ideal Gas Law**: - The ideal gas law is given by the equation: \[ PV = nRT \] - Where: - \( P \) = pressure - \( V \) = volume - \( n \) = number of moles - \( R \) = ideal gas constant - \( T \) = temperature 3. **Calculate the Number of Moles**: - Rearranging the ideal gas law to find the number of moles (\( n \)): \[ n = \frac{PV}{RT} \] - Since pressure (\( P \)), volume (\( V \)), \( R \), and temperature (\( T \)) are the same for both flasks, we can conclude that the number of moles of gas in each flask is the same. 4. **Conclusion about the Number of Moles**: - Therefore, the number of moles in flask A (SO₃) is equal to the number of moles in flask B (CO): \[ n_A = n_B \] 5. **Analyze the Statements**: - The first statement claims A has twice the number of moles as B: **False**. - The second statement claims B has twice the number of moles as A: **False**. - The third statement claims A and B have equal number of moles: **True**. - The fourth statement claims B has twice the number of atoms as A: **False** (since SO₃ has 4 atoms and CO has 2 atoms). 6. **Final Answer**: - The correct statement is: **A and B have equal number of moles.**
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