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consider the reaction 2A(g) + B(g) hArr ...

consider the reaction `2A_(g) + B_(g) hArr 2C_(g)` for which `K_c = 350`. if 0.001` mole of each of the reactant and product are mix in a 2.0 L flux in the reaction quotient and spontaneous direction of the system will be

A

`Q_c `= 0.002, the equilibrium shifts to the left

B

`Q_c` = 2000, the equilibrium shifts to the left

C

`Q_c` =0.002, the equilibrium shifts to right

D

`Q_c` = 2000, the equilibrium shifts to right

Text Solution

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To solve the problem, we need to determine the reaction quotient \( Q \) for the given reaction and compare it with the equilibrium constant \( K_c \) to find the direction in which the reaction will proceed. ### Step-by-step Solution: 1. **Write the Reaction and Equilibrium Constant:** The reaction is given as: \[ 2A_{(g)} + B_{(g)} \rightleftharpoons 2C_{(g)} \] The equilibrium constant \( K_c \) for this reaction is given as \( K_c = 350 \). 2. **Determine Initial Moles:** We are given that 0.001 moles of each reactant and product are mixed in a 2.0 L flask. Therefore, the initial moles are: - Moles of \( A = 0.001 \) - Moles of \( B = 0.001 \) - Moles of \( C = 0.001 \) 3. **Calculate Initial Concentrations:** The concentration of each species can be calculated using the formula: \[ \text{Concentration} = \frac{\text{Moles}}{\text{Volume (L)}} \] For 2.0 L: \[ [A] = \frac{0.001}{2.0} = 0.0005 \, \text{M} \] \[ [B] = \frac{0.001}{2.0} = 0.0005 \, \text{M} \] \[ [C] = \frac{0.001}{2.0} = 0.0005 \, \text{M} \] 4. **Write the Expression for Reaction Quotient \( Q \):** The reaction quotient \( Q \) is calculated using the formula: \[ Q = \frac{[C]^2}{[A]^2[B]} \] Substituting the concentrations: \[ Q = \frac{(0.0005)^2}{(0.0005)^2 \cdot (0.0005)} = \frac{0.00000025}{0.00000025 \cdot 0.0005} \] Simplifying this: \[ Q = \frac{0.00000025}{0.000000125} = 2 \] 5. **Compare \( Q \) with \( K_c \):** Now we compare \( Q \) with \( K_c \): \[ Q = 2 \quad \text{and} \quad K_c = 350 \] Since \( Q < K_c \), the reaction will proceed in the forward direction to form more products. 6. **Conclusion:** The reaction will shift towards the right (favoring the formation of products \( C \)).
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