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Aqueous solution of which salt will not ...

Aqueous solution of which salt will not be hydrolysed?

A

Potassium nitrate

B

Potassium cyanide

C

Potassium formate

D

Potassium acetate

Text Solution

AI Generated Solution

The correct Answer is:
To determine which aqueous salt will not be hydrolyzed, we need to analyze the hydrolysis of the given salts. Hydrolysis refers to the reaction of a salt with water, which can lead to the formation of an acidic or basic solution depending on the nature of the salt. ### Step-by-Step Solution: 1. **Identify the Salts**: The salts given in the question are: - Potassium nitrate (KNO3) - Potassium cyanide (KCN) - Potassium formate (HCOOK) - Potassium acetate (CH3COOK) 2. **Understand Hydrolysis**: Hydrolysis occurs when a salt reacts with water to form an acid and a base. The extent of hydrolysis depends on whether the salt is derived from a strong acid and a strong base, a weak acid and a strong base, a strong acid and a weak base, or a weak acid and a weak base. 3. **Analyze Each Salt**: - **Potassium Nitrate (KNO3)**: - KNO3 is formed from the strong acid (HNO3) and the strong base (KOH). - Hydrolysis: KNO3 + H2O → KOH + HNO3 - Since both components are strong, KNO3 does not undergo hydrolysis. - **Potassium Cyanide (KCN)**: - KCN is formed from the strong base (KOH) and the weak acid (HCN). - Hydrolysis: KCN + H2O → KOH + HCN - This salt will undergo hydrolysis because it contains a weak acid. - **Potassium Formate (HCOOK)**: - HCOOK is formed from the strong base (KOH) and the weak acid (HCOOH). - Hydrolysis: HCOOK + H2O → KOH + HCOOH - This salt will also undergo hydrolysis due to the weak acid. - **Potassium Acetate (CH3COOK)**: - CH3COOK is formed from the strong base (KOH) and the weak acid (CH3COOH). - Hydrolysis: CH3COOK + H2O → KOH + CH3COOH - This salt will also undergo hydrolysis because it contains a weak acid. 4. **Conclusion**: Among the four salts analyzed, only potassium nitrate (KNO3) does not undergo hydrolysis because it is a salt derived from a strong acid and a strong base. ### Final Answer: **Potassium nitrate (KNO3) will not be hydrolyzed.**
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