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Which among the following is a paramagne...

Which among the following is a paramagnetic compound?

A

`N_2O`

B

NO

C

`N_2O_3`

D

`N_2O_4`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which among the given compounds is paramagnetic, we need to analyze the sum of the valence electrons for each compound and check if it is odd or even. ### Step-by-Step Solution: 1. **Identify the Compounds**: The compounds given are: - N2O - NO - N2O3 - N2O4 2. **Calculate Valence Electrons for Each Compound**: - **N2O**: - Nitrogen (N) has 5 valence electrons and there are 2 nitrogen atoms: \( 5 \times 2 = 10 \) - Oxygen (O) has 6 valence electrons: \( 6 \) - Total = \( 10 + 6 = 16 \) (even) - **NO**: - Nitrogen (N) has 5 valence electrons: \( 5 \) - Oxygen (O) has 6 valence electrons: \( 6 \) - Total = \( 5 + 6 = 11 \) (odd) - **N2O3**: - Nitrogen (N) has 5 valence electrons and there are 2 nitrogen atoms: \( 5 \times 2 = 10 \) - Oxygen (O) has 6 valence electrons and there are 3 oxygen atoms: \( 6 \times 3 = 18 \) - Total = \( 10 + 18 = 28 \) (even) - **N2O4**: - Nitrogen (N) has 5 valence electrons and there are 2 nitrogen atoms: \( 5 \times 2 = 10 \) - Oxygen (O) has 6 valence electrons and there are 4 oxygen atoms: \( 6 \times 4 = 24 \) - Total = \( 10 + 24 = 34 \) (even) 3. **Determine Magnetic Properties**: - A compound is **paramagnetic** if the sum of its valence electrons is **odd** (indicating the presence of unpaired electrons). - A compound is **diamagnetic** if the sum of its valence electrons is **even** (indicating all electrons are paired). 4. **Conclusion**: - From the calculations: - N2O: 16 (diamagnetic) - NO: 11 (paramagnetic) - N2O3: 28 (diamagnetic) - N2O4: 34 (diamagnetic) - Therefore, the only paramagnetic compound among the options is **NO**. ### Final Answer: The paramagnetic compound is **NO**.
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