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Acetylation of glucose with acetic anhyd...

Acetylation of glucose with acetic anhydride gives

A

Glucose hexaacetate

B

Glucose pentaacetate

C

Glucose butaacetate

D

Glucose diacetate

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the acetylation of glucose with acetic anhydride, we can follow these steps: ### Step 1: Understand the Reactants - **Glucose** is a six-carbon sugar with multiple hydroxyl (–OH) groups. - **Acetic anhydride** is a reagent used to introduce acetyl groups (–COCH3) into organic molecules. ### Step 2: Identify the Reaction - Acetylation involves the reaction of glucose with acetic anhydride. Each hydroxyl group on glucose can react with an acetyl group from acetic anhydride. ### Step 3: Determine the Number of Hydroxyl Groups - Glucose has five hydroxyl groups (–OH) that can be acetylated. The structure of glucose is: - C1: Aldehyde group (–CHO) - C2 to C5: Hydroxyl groups (–OH) - C6: Methyl group (–CH2OH) ### Step 4: Calculate the Possible Acetylation Products - Since glucose has five hydroxyl groups, it can theoretically be fully acetylated to form glucose pentaacetate, where all five –OH groups are replaced by –OCOCH3 groups. ### Step 5: Write the Product Structure - The product of the complete acetylation of glucose would be glucose pentaacetate, which can be represented as: - C1: Acetyl group (–COCH3) - C2 to C5: Acetyl groups (–COCH3) - C6: Acetyl group (–COCH3) ### Step 6: Identify the Correct Answer - The correct answer to the question is **B. glucose pentaacetate**, as it is the product formed when all five hydroxyl groups of glucose are acetylated. ### Final Answer: - Acetylation of glucose with acetic anhydride gives **glucose pentaacetate**. ---
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Knowledge Check

  • Glucose reacts with acetic anhydride to form

    A
    3
    B
    5
    C
    4
    D
    1
  • Cellulose upon acetylation with excess acetic anhydride/ H_(2)SO_(4) (catalytic) gives cellulose triacetate whose structure is

    A
    B
    C
    D
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