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The average speed of nitrogen molecules ...

The average speed of nitrogen molecules in a gas is `v`. If the temperature is doubled and the `N_(2)` molecule dissociate into nitrogen atoms, then the average speed will be

A

`v`

B

`vsqrt(2)`

C

`2v`

D

`4v`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze how the average speed of nitrogen molecules changes when the temperature is doubled and the nitrogen molecules dissociate into nitrogen atoms. ### Step-by-Step Solution: 1. **Initial Conditions**: - Let the average speed of nitrogen molecules (N₂) be \( v \). - The initial temperature is \( T \). 2. **Molar Mass of Nitrogen Molecule**: - The molar mass of nitrogen (N₂) is \( 28 \, \text{g/mol} \) (since each nitrogen atom has a mass of \( 14 \, \text{g/mol} \)). 3. **Average Speed Formula**: - The root mean square speed \( v_{\text{rms}} \) of gas molecules is given by the formula: \[ v_{\text{rms}} = \sqrt{\frac{3RT}{M}} \] where \( R \) is the universal gas constant, \( T \) is the temperature, and \( M \) is the molar mass. 4. **Average Speed of Nitrogen Molecules (N₂)**: - For nitrogen molecules: \[ v = \sqrt{\frac{3RT}{28}} \] 5. **New Conditions After Temperature is Doubled**: - When the temperature is doubled, the new temperature \( T' = 2T \). 6. **Dissociation of Nitrogen Molecules**: - When N₂ dissociates into nitrogen atoms (N), the molar mass of nitrogen atoms is \( 14 \, \text{g/mol} \). 7. **Average Speed of Nitrogen Atoms (N)**: - The average speed of nitrogen atoms at the new temperature can be calculated as: \[ v' = \sqrt{\frac{3R(2T)}{14}} \] 8. **Simplifying the Expression**: - Substitute \( T' = 2T \) into the equation: \[ v' = \sqrt{\frac{3R(2T)}{14}} = \sqrt{\frac{6RT}{14}} = \sqrt{\frac{3RT}{7}} \] 9. **Relating the Speeds**: - We can relate \( v' \) to \( v \): \[ v = \sqrt{\frac{3RT}{28}} \] - To find the ratio: \[ \frac{v'}{v} = \frac{\sqrt{\frac{3RT}{7}}}{\sqrt{\frac{3RT}{28}}} = \sqrt{\frac{28}{7}} = \sqrt{4} = 2 \] 10. **Conclusion**: - Therefore, the average speed of nitrogen atoms after the temperature is doubled and the molecules dissociate is: \[ v' = 2v \] ### Final Answer: The average speed will be \( 2v \).
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