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One mole of an ideal gas undergoes a pro...

One mole of an ideal gas undergoes a process in which `T = T_(0) + aV^(3)`, where `T_(0)` and `a` are positive constants and V is molar volume. The volume for which pressure with be minimum is

A

`((T_(0))/(2a))^(1//3)`

B

`((T_(0))/(3a))^(1//3)`

C

`((a)/(2T_(0)))^(2//3)`

D

`((a)/(3T_(0)))^(2//3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the volume for which the pressure of one mole of an ideal gas is at a minimum, given the relationship between temperature and volume as \( T = T_0 + aV^3 \). ### Step-by-Step Solution: 1. **Start with the Ideal Gas Law**: The ideal gas law is given by: \[ PV = nRT \] For one mole of gas (\( n = 1 \)), this simplifies to: \[ PV = RT \] 2. **Substitute the Expression for Temperature**: We know from the problem that: \[ T = T_0 + aV^3 \] Substituting this into the ideal gas equation gives: \[ PV = R(T_0 + aV^3) \] 3. **Rearranging the Equation**: Rearranging the equation, we have: \[ P = \frac{R(T_0 + aV^3)}{V} \] This can be expressed as: \[ P = \frac{RT_0}{V} + RaV^2 \] 4. **Finding the Condition for Minimum Pressure**: To find the volume at which pressure is minimized, we need to take the derivative of \( P \) with respect to \( V \) and set it to zero: \[ \frac{dP}{dV} = -\frac{RT_0}{V^2} + 2RaV = 0 \] 5. **Setting the Derivative to Zero**: Setting the derivative equal to zero gives: \[ -\frac{RT_0}{V^2} + 2RaV = 0 \] Rearranging this, we get: \[ 2RaV = \frac{RT_0}{V^2} \] 6. **Multiplying through by \( V^2 \)**: Multiplying both sides by \( V^2 \) results in: \[ 2RaV^3 = RT_0 \] 7. **Solving for \( V^3 \)**: Dividing both sides by \( 2aR \): \[ V^3 = \frac{T_0}{2a} \] 8. **Taking the Cube Root**: Taking the cube root gives us: \[ V = \left(\frac{T_0}{2a}\right)^{1/3} \] ### Final Answer: The volume for which pressure will be minimum is: \[ V = \left(\frac{T_0}{2a}\right)^{1/3} \]
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