Home
Class 12
CHEMISTRY
Draw two anomers of D-fructose....

Draw two anomers of D-fructose.

Text Solution

AI Generated Solution

The correct Answer is:
To draw the two anomers of D-fructose, we will follow these steps: ### Step 1: Understand the Structure of D-Fructose D-fructose is a ketohexose, meaning it has six carbon atoms and a ketone functional group. In its cyclic form, fructose can exist in two anomeric forms based on the orientation of the hydroxyl group (-OH) at the anomeric carbon (carbon 2 in fructose). ### Step 2: Draw the Cyclic Structure of D-Fructose 1. Start by drawing a six-membered ring structure (furanose form) for D-fructose. 2. Place the ketone group at carbon 2. 3. The carbon atoms will be numbered from 1 to 6, with carbon 1 being the carbon that is part of the carbonyl group in the open-chain form. ### Step 3: Identify the Anomeric Carbon In D-fructose, the anomeric carbon is carbon 2. The two anomers differ in the orientation of the hydroxyl group attached to this carbon. ### Step 4: Draw the Alpha Anomer (α-D-Fructofuranose) 1. In the alpha anomer, the hydroxyl group (-OH) on the anomeric carbon (C2) is positioned below the plane of the ring. 2. Draw the ring with the -OH group on carbon 2 pointing downwards. ### Step 5: Draw the Beta Anomer (β-D-Fructofuranose) 1. In the beta anomer, the hydroxyl group (-OH) on the anomeric carbon (C2) is positioned above the plane of the ring. 2. Draw the ring with the -OH group on carbon 2 pointing upwards. ### Step 6: Finalize the Structures 1. Ensure that all other substituents (like CH2OH on carbon 6) are correctly placed. 2. Label each structure clearly as α-D-fructofuranose and β-D-fructofuranose. ### Final Structures: - **Alpha-D-Fructofuranose**: The -OH group on C2 is down. - **Beta-D-Fructofuranose**: The -OH group on C2 is up.

To draw the two anomers of D-fructose, we will follow these steps: ### Step 1: Understand the Structure of D-Fructose D-fructose is a ketohexose, meaning it has six carbon atoms and a ketone functional group. In its cyclic form, fructose can exist in two anomeric forms based on the orientation of the hydroxyl group (-OH) at the anomeric carbon (carbon 2 in fructose). ### Step 2: Draw the Cyclic Structure of D-Fructose 1. Start by drawing a six-membered ring structure (furanose form) for D-fructose. 2. Place the ketone group at carbon 2. ...
Promotional Banner

Topper's Solved these Questions

  • BIOMOLECULES

    RESONANCE ENGLISH|Exercise Ex-2(Single correct)Part-II|17 Videos
  • BIOMOLECULES

    RESONANCE ENGLISH|Exercise Ex-2(More correct)Part-II|14 Videos
  • BIOMOLECULES

    RESONANCE ENGLISH|Exercise Ex-1(Assertion/Reasoning)Part-III|10 Videos
  • BASIC CONCEPTS

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(BASIC CONCEPTS)|27 Videos
  • BIOMOLECULES & POLYMER

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Biomolecules & Polymer)|34 Videos

Similar Questions

Explore conceptually related problems

Name the anomers of glucose. How do they differ and what is the chief consequence of this difference ?

Select the polymer of fructose.

Net yield of ATP when two molecules of fructose -1,6- bisphosphate is oxidized to pyruvic acid through glycolytic way in absence of O_2 is

Draw two isomers of Butene and name them.

The fischer projection of L-fructose is given below, write the fischer projection of D-fructose. .

Which one is polymer of fructose ?

Which is the most stable anomer of glucose?

What are anomers ?

D- Fructose with dil. NaOH undergoes a reversible isomerisation and is converted to a mixure of D- glucose, D- mannose and S- fructose. Statement II: This reaction is known as Lobryde Bruyn-van Ekenstein rearrangement.

Number of asymmetric carbon atoms in fructose

RESONANCE ENGLISH-BIOMOLECULES-Ex-2(Subjective)Part-I
  1. Classify the following monosaccharides in proper aldoses and ketose.

    Text Solution

    |

  2. Write the anomer, the epimer, enantiomer of the following aldose, Als...

    Text Solution

    |

  3. Draw two anomers of D-fructose.

    Text Solution

    |

  4. The specific rotation of two glucose anomers are alpha = + 110^(@) and...

    Text Solution

    |

  5. Consider an amylose chain of 4000 glucose unit. At how many cleavage r...

    Text Solution

    |

  6. The density of methane at 3.0 atm pressure and 27^0C is :

    Text Solution

    |

  7. The density of methane at 5.0 atm pressure and 27^0C is :

    Text Solution

    |

  8. Find rms speed of oxygen molecules at temperature 27^(@)C.

    Text Solution

    |

  9. On which side of neutrality (pH-7), the isoelectric point of the follo...

    Text Solution

    |

  10. Glutomic acid (A) has isoelectric point 3.22 (a) What is the most li...

    Text Solution

    |

  11. The density of Carbon dioxide at 3.0 atm pressure and 27^0C is :

    Text Solution

    |

  12. The density of Carbon dioxide at 5.0 atm pressure and 27^0C is :

    Text Solution

    |

  13. The density of Carbon dioxide at 4.0 atm pressure and 27^0C is :

    Text Solution

    |

  14. Distinguish between (a) Glycine and acetamide (b) alpha -, beta - ...

    Text Solution

    |

  15. An octapeptide (Mol.wt = 516 g) on complete hydrolysis given glycine a...

    Text Solution

    |

  16. Give the amino acid sequence of the following polypeptides using the d...

    Text Solution

    |

  17. Glutamic acid has lower isoelectric point while glutamine H(2)N-overse...

    Text Solution

    |

  18. Give the following conversion acetaldehyde rarr alanine.

    Text Solution

    |

  19. Complete the following reactions

    Text Solution

    |

  20. The density of Carbon dioxide at 6.0 atm pressure and 27^0C is :

    Text Solution

    |