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The spin only magnetic of Cr^(3+) in aqu...

The spin only magnetic of `Cr^(3+)` in aqueous solution would be `:`

A

`sqrt(3) B.M.`

B

`sqrt(15)B.M.`

C

`sqrt(8)B.M.`

D

`sqrt(35)B.M.`

Text Solution

AI Generated Solution

The correct Answer is:
To find the spin-only magnetic moment of `Cr^(3+)` in aqueous solution, we can follow these steps: ### Step 1: Determine the Atomic Number and Electron Configuration of Chromium - Chromium (Cr) has an atomic number of 24. - The electron configuration of neutral chromium is: \[ [Ar] 4s^1 3d^5 \] ### Step 2: Identify the Oxidation State - In the question, chromium is in the +3 oxidation state (`Cr^(3+)`). - This means that it has lost 3 electrons. ### Step 3: Adjust the Electron Configuration for `Cr^(3+)` - When chromium loses 3 electrons, it loses the 1 electron from the 4s orbital and 2 electrons from the 3d orbital. - The electron configuration for `Cr^(3+)` will be: \[ [Ar] 3d^3 \] - This indicates that there are 3 electrons in the 3d subshell. ### Step 4: Determine the Number of Unpaired Electrons - In the `3d^3` configuration, all three electrons are unpaired. - Therefore, the number of unpaired electrons (n) is 3. ### Step 5: Use the Formula for Spin-Only Magnetic Moment - The formula for calculating the spin-only magnetic moment (μ) is: \[ \mu = \sqrt{n(n + 2)} \] where n is the number of unpaired electrons. ### Step 6: Substitute the Value of n into the Formula - Substituting n = 3 into the formula: \[ \mu = \sqrt{3(3 + 2)} = \sqrt{3 \times 5} = \sqrt{15} \] ### Step 7: Conclusion - The spin-only magnetic moment of `Cr^(3+)` in aqueous solution is: \[ \mu = \sqrt{15} \, \text{BM} \] ### Final Answer - The correct option is the one that states the magnetic moment is \(\sqrt{15} \, \text{BM}\). ---

To find the spin-only magnetic moment of `Cr^(3+)` in aqueous solution, we can follow these steps: ### Step 1: Determine the Atomic Number and Electron Configuration of Chromium - Chromium (Cr) has an atomic number of 24. - The electron configuration of neutral chromium is: \[ [Ar] 4s^1 3d^5 \] ...
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