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In the emission spectrum of H- atom fro...

In the emission spectrum of `H-` atom from energy level `'n'` to ground state in one more step, no line belonging to the Brackett series is observed. The wave number of lines belonging to Balmer series may be

A

`(8R)/(9),(5R)/(36)`

B

`(3R)/(16),(8R)/(9)`

C

`(5R)/(36),(3R)/(16)`

D

`(3R)/(4),(3R)/(16)`

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The correct Answer is:
To solve the question regarding the emission spectrum of the H- atom and the wave numbers of lines belonging to the Balmer series, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Series**: - The Balmer series corresponds to transitions where the final energy level (n1) is 2. The transitions can occur from n = 3, 4, 5, etc., to n = 2. 2. **Formula for Wave Number**: - The wave number (ṽ) is given by the formula: \[ ṽ = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] - Here, R is the Rydberg constant, \( n_1 \) is the lower energy level (2 for Balmer series), and \( n_2 \) is the higher energy level (3, 4, etc.). 3. **Calculate Wave Number for Transition from n=3 to n=2**: - For the transition from n=3 to n=2: \[ ṽ = R \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = R \left( \frac{1}{4} - \frac{1}{9} \right) \] - Finding a common denominator (36): \[ ṽ = R \left( \frac{9}{36} - \frac{4}{36} \right) = R \left( \frac{5}{36} \right) \] 4. **Calculate Wave Number for Transition from n=4 to n=2**: - For the transition from n=4 to n=2: \[ ṽ = R \left( \frac{1}{2^2} - \frac{1}{4^2} \right) = R \left( \frac{1}{4} - \frac{1}{16} \right) \] - Finding a common denominator (16): \[ ṽ = R \left( \frac{4}{16} - \frac{1}{16} \right) = R \left( \frac{3}{16} \right) \] 5. **Conclusion**: - The wave numbers for the transitions in the Balmer series from n=3 to n=2 and from n=4 to n=2 are: - From n=3 to n=2: \( ṽ = \frac{5R}{36} \) - From n=4 to n=2: \( ṽ = \frac{3R}{16} \) ### Final Answer: The wave numbers of lines belonging to the Balmer series may be \( \frac{5R}{36} \) and \( \frac{3R}{16} \).

To solve the question regarding the emission spectrum of the H- atom and the wave numbers of lines belonging to the Balmer series, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Series**: - The Balmer series corresponds to transitions where the final energy level (n1) is 2. The transitions can occur from n = 3, 4, 5, etc., to n = 2. 2. **Formula for Wave Number**: ...
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