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According to Bohr's theory, the ratio of...

According to Bohr's theory, the ratio of electrostatic force of attraction acting on electron `3^(rd)` orbit of `He^(+)` ion and `2^(nd)` orbit of `Li^(2+)` ion is `((3)/(2))^(x)`. Then, the value of `x` is `:`

A

7

B

-6

C

6

D

-7

Text Solution

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The correct Answer is:
To solve the problem, we will follow these steps: ### Step 1: Understand the electrostatic force formula According to Bohr's theory, the electrostatic force of attraction (F) acting on an electron in a given orbit can be expressed as: \[ F = \frac{k \cdot Z^2}{n^4} \] where: - \( k \) is a constant, - \( Z \) is the atomic number of the ion, - \( n \) is the principal quantum number (the orbit number). ### Step 2: Calculate the electrostatic force for the He\(^+\) ion in the 3rd orbit For the He\(^+\) ion: - \( Z = 2 \) (Helium has an atomic number of 2) - \( n = 3 \) Using the formula: \[ F_{He^+} = \frac{k \cdot 2^2}{3^4} = \frac{k \cdot 4}{81} \] ### Step 3: Calculate the electrostatic force for the Li\(^{2+}\) ion in the 2nd orbit For the Li\(^{2+}\) ion: - \( Z = 3 \) (Lithium has an atomic number of 3) - \( n = 2 \) Using the formula: \[ F_{Li^{2+}} = \frac{k \cdot 3^2}{2^4} = \frac{k \cdot 9}{16} \] ### Step 4: Find the ratio of the electrostatic forces Now, we need to find the ratio of the forces: \[ \text{Ratio} = \frac{F_{He^+}}{F_{Li^{2+}}} = \frac{\frac{k \cdot 4}{81}}{\frac{k \cdot 9}{16}} \] This simplifies to: \[ \text{Ratio} = \frac{4}{81} \cdot \frac{16}{9} = \frac{64}{729} \] ### Step 5: Express the ratio in terms of \(\left(\frac{3}{2}\right)^x\) We know from the problem statement that: \[ \frac{64}{729} = \left(\frac{3}{2}\right)^x \] ### Step 6: Rewrite \(64\) and \(729\) in terms of powers We can express \(64\) and \(729\) as: - \( 64 = 2^6 \) - \( 729 = 3^6 \) Thus, we can rewrite the ratio as: \[ \frac{2^6}{3^6} = \left(\frac{2}{3}\right)^6 \] ### Step 7: Equate and solve for \(x\) Now we have: \[ \left(\frac{2}{3}\right)^6 = \left(\frac{3}{2}\right)^x \] Taking the reciprocal of \(\frac{2}{3}\): \[ \left(\frac{3}{2}\right)^{-6} = \left(\frac{3}{2}\right)^x \] This implies: \[ x = -6 \] ### Final Answer Thus, the value of \(x\) is: \[ \boxed{-6} \]

To solve the problem, we will follow these steps: ### Step 1: Understand the electrostatic force formula According to Bohr's theory, the electrostatic force of attraction (F) acting on an electron in a given orbit can be expressed as: \[ F = \frac{k \cdot Z^2}{n^4} \] where: - \( k \) is a constant, - \( Z \) is the atomic number of the ion, ...
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