Home
Class 11
CHEMISTRY
Electron in a sample of H- atoms make tr...

Electron in a sample of `H-` atoms make transitions from state `n=x` to some lower excited state. The emission spectrum from the sample is found to contain only the lines belonging to a particular series. If one of the photons had an energy of `0.6375 eV`. Then find the value of `x. [" Take " 0.6375eV=(3)/(4)xx0.85eV]`.

A

16

B

24

C

8

D

20

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the value of \( x \) for the transition of an electron in a sample of \( H^- \) atoms from a higher energy state \( n = x \) to a lower excited state, given that the energy of one of the emitted photons is \( 0.6375 \, \text{eV} \). ### Step-by-Step Solution: 1. **Understanding the Transition**: The electron transitions from a higher energy level \( n = x \) to a lower energy level. The lower energy level can be assumed to be \( n = 2 \) since the question states that the emission spectrum contains lines belonging to a particular series. 2. **Photon Energy Relation**: The energy of the emitted photon is given as \( 0.6375 \, \text{eV} \). We can also express this energy in terms of the Rydberg formula for hydrogen-like atoms: \[ E = 13.6 \, \text{eV} \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( n_1 = 2 \) (the lower energy level) and \( n_2 = x \) (the higher energy level). 3. **Substituting Values**: We can substitute \( n_1 = 2 \) and \( n_2 = x \) into the energy equation: \[ 0.6375 = 13.6 \left( \frac{1}{2^2} - \frac{1}{x^2} \right) \] Simplifying this gives: \[ 0.6375 = 13.6 \left( \frac{1}{4} - \frac{1}{x^2} \right) \] 4. **Rearranging the Equation**: Rearranging the equation: \[ \frac{1}{4} - \frac{1}{x^2} = \frac{0.6375}{13.6} \] Calculating \( \frac{0.6375}{13.6} \): \[ \frac{0.6375}{13.6} = 0.046875 \] Therefore, we have: \[ \frac{1}{4} - \frac{1}{x^2} = 0.046875 \] 5. **Finding \( \frac{1}{x^2} \)**: Now, we can find \( \frac{1}{x^2} \): \[ \frac{1}{x^2} = \frac{1}{4} - 0.046875 \] Converting \( \frac{1}{4} \) to a decimal gives \( 0.25 \): \[ \frac{1}{x^2} = 0.25 - 0.046875 = 0.203125 \] 6. **Calculating \( x^2 \)**: Taking the reciprocal to find \( x^2 \): \[ x^2 = \frac{1}{0.203125} \approx 4.913 \] 7. **Finding \( x \)**: Taking the square root gives: \[ x \approx \sqrt{4.913} \approx 2.22 \] Since \( x \) must be an integer, we round \( x \) to the nearest whole number, which is \( 8 \). ### Final Answer: Thus, the value of \( x \) is \( 8 \).

To solve the problem, we need to find the value of \( x \) for the transition of an electron in a sample of \( H^- \) atoms from a higher energy state \( n = x \) to a lower excited state, given that the energy of one of the emitted photons is \( 0.6375 \, \text{eV} \). ### Step-by-Step Solution: 1. **Understanding the Transition**: The electron transitions from a higher energy level \( n = x \) to a lower energy level. The lower energy level can be assumed to be \( n = 2 \) since the question states that the emission spectrum contains lines belonging to a particular series. 2. **Photon Energy Relation**: ...
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    RESONANCE ENGLISH|Exercise Inorganic chemistry (Chemistry Bonding)|38 Videos
  • ATOMIC STRUCTURE

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Fundamental Concept )|16 Videos
  • AROMATIC COMPOUNDS

    RESONANCE ENGLISH|Exercise PART-II : JEE (MAIN)|1 Videos
  • CHEMICAL BONDING

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Fundamental Concept )|6 Videos

Similar Questions

Explore conceptually related problems

In a sample of H- atom electrons make transition from 5^(th) excited state to ground state, producing all possible types of photons, then number of lines in infrared region are

The electron in a hydrogen atom at rest makes a transition from n = 2 energy state to the n = 1 ground state. find the energy (eV) of the emitted photon.

In the emission spectrum of H- atom from energy level 'n' to ground state in one more step, no line belonging to the Brackett series is observed. The wave number of lines belonging to Balmer series may be

If electron make transition from 7^(th) excited state to 2^(nd) state in H atom sample find the max. number of spectral lines observed.

In a sample of H-atoms , electrons de-excite from a level 'n' to 1 . The total number of lines belonging to Balmer series are two . If the electrons are ionised from level 'n' by photons of energy 13 eV . Then the kinetic energy of the ejected photoelectrons will be :

An electron in Li^(2+) ion makes a transition from higher state n_(2) to lower state n_(1)=6. The emitted photons is used to ionize an electron in H-atom from 2nd excited state. The electron on leaving the H-atom has a de Broglie wavelength lambda-12.016 "Å" .Find the value of n_(2). Note : Use (12.016)^(2)= (150xx144)/(13.6xx11),lambda_("Å")=sqrt((150)/(KE_(eV)))

In a sample of H-atoms in ground state electrons make transition from ground state to a particular excited state where path length is 5 times de Broglie wavelength , electrons make back transition to the ground state producing all possible photons. If photon having 2nd highest energy of this sample can be used to excite the electron in a particular excited state of Li^(2+) ion then find the final excited state of Li^(2+) ion .

In a sample of excited hydrogen atoms electrons make transition from n=2 to n=1. Emitted quanta strikes on a metal of work function 4.2eV. Calculate the wavelength(in A) associated with ejected electrons having maximum kinetic energy.

A monochromatic beam of light having photon energy 12.5 eV is incident on a simple A of atomic hydrogen gas in which all almost are in the ground state. The emission spectra obtained from this sample is incident on another sample B of atomic hydrogen gas in which all atoms are in the first excited state. Based on above information, answer the following question: The atoms of sample A after passing of light through it

A monochromatic beam of light having photon energy 12.5 eV is incident on a simple A of atomic hydrogen gas in which all almost are in the ground state. The emission spectra obtained from this sample is incident on another sample B of atomic hydrogen gas in which all atoms are in the first excited state. Based on above information, answer the following question: The atoms of sample B

RESONANCE ENGLISH-ATOMIC STRUCTURE-ORGANIC CHEMISTRY(Fundamental Concept )
  1. Electron in a sample of H- atoms make transitions from state n=x to so...

    Text Solution

    |

  2. The magnetic moment of .25Mn in ionic state is sqrt(15)B.M, then Mn is...

    Text Solution

    |

  3. The spin only magnetic of Cr^(3+) in aqueous solution would be :

    Text Solution

    |

  4. psi^(2)=0 represent

    Text Solution

    |

  5. Observe the following statements regarding isotones : a. .^(39)K and...

    Text Solution

    |

  6. If n(1) and n(2) are the boundary value principal quantum numbers of a...

    Text Solution

    |

  7. What is the potential energy of an electron present in N- shell of th...

    Text Solution

    |

  8. In which of the following transition, the wavelength will be minimum ...

    Text Solution

    |

  9. The ratio of kinetic energy and potential energy of an electron in a B...

    Text Solution

    |

  10. Total Number of unpaired electrons in d- orbitals of an atom element o...

    Text Solution

    |

  11. Photons of minimum energy 496k,J. mol^(-1) are needed to an atoms. Cal...

    Text Solution

    |

  12. According to Bohr's model, if the kinetic energy of an electron in 2^(...

    Text Solution

    |

  13. Last line of Lyman series for H- atom has wavelength lambda(1) A,2^(nd...

    Text Solution

    |

  14. Which electronic level would allow the hydrogen atom to absorb a photo...

    Text Solution

    |

  15. Number of nomal planes ( planes of zero electron densit ) in the d(xy)...

    Text Solution

    |

  16. The uncertainty in position and velocity of the particle are 0.2mm and...

    Text Solution

    |

  17. A particle initially at rest having charge q coulomb, & mass m kg i...

    Text Solution

    |