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A V dm^(3) flask contains gas A and anot...

A `V dm^(3)` flask contains gas `A` and another flask of `2V dm^(3)` contains gas `B` at the same temperature If density of gas `A` is `3.0gdm^(-3)` and of gas `B` is `1.5g dm^(-3)` and mo1 wt of `A =1//2` wt pf `B` then the ratio of pressure exerted by gases is .

A

`(P_(A))/(P_(B))=2`

B

`(P_(A))/(P_(B))=1`

C

`(P_(A))/(P_(B))=4`

D

`(P_(A))/(P_(B))=3`

Text Solution

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The correct Answer is:
To solve the problem step by step, we will use the ideal gas law and the relationships between density, molecular weight, and pressure. ### Step 1: Write down the known values - Volume of gas A, \( V_A = V \, \text{dm}^3 \) - Volume of gas B, \( V_B = 2V \, \text{dm}^3 \) - Density of gas A, \( D_A = 3.0 \, \text{g/dm}^3 \) - Density of gas B, \( D_B = 1.5 \, \text{g/dm}^3 \) - Molecular weight of gas A, \( M_A = \frac{1}{2} M_B \) ### Step 2: Use the ideal gas equation The ideal gas equation is given by: \[ PV = nRT \] where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the gas constant, and \( T \) is temperature. ### Step 3: Relate density to pressure The number of moles \( n \) can be expressed in terms of mass and molecular weight: \[ n = \frac{W}{M} \] where \( W \) is the mass of the gas. Using the definition of density \( D \): \[ D = \frac{W}{V} \implies W = D \cdot V \] Substituting this into the ideal gas equation gives: \[ P = \frac{D \cdot V \cdot R \cdot T}{M} \] ### Step 4: Write the expressions for pressures of gases A and B For gas A: \[ P_A = \frac{D_A \cdot V_A \cdot R \cdot T}{M_A} \] For gas B: \[ P_B = \frac{D_B \cdot V_B \cdot R \cdot T}{M_B} \] ### Step 5: Substitute the known values Substituting the known values into the equations: \[ P_A = \frac{3.0 \cdot V \cdot R \cdot T}{M_A} \] \[ P_B = \frac{1.5 \cdot 2V \cdot R \cdot T}{M_B} \] ### Step 6: Substitute \( M_A \) in terms of \( M_B \) Since \( M_A = \frac{1}{2} M_B \): \[ P_A = \frac{3.0 \cdot V \cdot R \cdot T}{\frac{1}{2} M_B} = \frac{6.0 \cdot V \cdot R \cdot T}{M_B} \] ### Step 7: Write the expression for \( P_B \) Now substituting \( P_B \): \[ P_B = \frac{1.5 \cdot 2V \cdot R \cdot T}{M_B} = \frac{3.0 \cdot V \cdot R \cdot T}{M_B} \] ### Step 8: Find the ratio of pressures Now, we can find the ratio of pressures \( \frac{P_A}{P_B} \): \[ \frac{P_A}{P_B} = \frac{\frac{6.0 \cdot V \cdot R \cdot T}{M_B}}{\frac{3.0 \cdot V \cdot R \cdot T}{M_B}} = \frac{6.0}{3.0} = 2 \] ### Step 9: Conclusion The ratio of the pressures exerted by gases A and B is: \[ \frac{P_A}{P_B} = 2 \]

To solve the problem step by step, we will use the ideal gas law and the relationships between density, molecular weight, and pressure. ### Step 1: Write down the known values - Volume of gas A, \( V_A = V \, \text{dm}^3 \) - Volume of gas B, \( V_B = 2V \, \text{dm}^3 \) - Density of gas A, \( D_A = 3.0 \, \text{g/dm}^3 \) - Density of gas B, \( D_B = 1.5 \, \text{g/dm}^3 \) - Molecular weight of gas A, \( M_A = \frac{1}{2} M_B \) ...
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