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In which of the following molecule// ion...

In which of the following molecule`//` ion all the bonds are equal?

A

`SiF_(4)`

B

`IF_(7)`

C

`ClF_(3)`

D

`PCl_(5)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given molecules or ions has all equal bonds, we will analyze each option step by step. ### Step 1: Analyze SiF4 - **Structure**: SiF4 (Silicon Tetrafluoride) is a tetrahedral molecule. - **Hybridization**: The hybridization can be calculated as follows: - Silicon (Si) has 4 valence electrons. - There are 4 fluorine (F) atoms, each contributing 1 electron. - Total = 4 (Si) + 4 (F) = 8 electrons. - Hybridization = 1/2 * (8) = 4, which corresponds to sp³ hybridization. - **Bond Characteristics**: In sp³ hybridization, all bond lengths are equal, and all angles are also equal. **Conclusion for SiF4**: All bonds in SiF4 are equal. ### Step 2: Analyze IF7 - **Structure**: IF7 (Iodine Heptafluoride) has a pentagonal bipyramidal shape. - **Hybridization**: The hybridization can be calculated as follows: - Iodine (I) has 7 valence electrons. - There are 7 fluorine (F) atoms. - Total = 7 (I) + 7 (F) = 14 electrons. - Hybridization = 1/2 * (14) = 7, which corresponds to sp³d³ hybridization. - **Bond Characteristics**: In a pentagonal bipyramidal structure, the axial bonds are longer than the equatorial bonds. **Conclusion for IF7**: Not all bonds are equal. ### Step 3: Analyze ClF3 - **Structure**: ClF3 (Chlorine Trifluoride) has a T-shaped structure. - **Hybridization**: The hybridization can be calculated as follows: - Chlorine (Cl) has 7 valence electrons. - There are 3 fluorine (F) atoms. - Total = 7 (Cl) + 3 (F) = 10 electrons. - Hybridization = 1/2 * (10) = 5, which corresponds to sp³d hybridization. - **Bond Characteristics**: In a T-shaped structure, the axial bonds are longer than the equatorial bonds. **Conclusion for ClF3**: Not all bonds are equal. ### Step 4: Analyze PCl5 - **Structure**: PCl5 (Phosphorus Pentachloride) has a trigonal bipyramidal structure. - **Hybridization**: The hybridization can be calculated as follows: - Phosphorus (P) has 5 valence electrons. - There are 5 chlorine (Cl) atoms. - Total = 5 (P) + 5 (Cl) = 10 electrons. - Hybridization = 1/2 * (10) = 5, which corresponds to sp³d hybridization. - **Bond Characteristics**: In a trigonal bipyramidal structure, the axial bonds are longer than the equatorial bonds. **Conclusion for PCl5**: Not all bonds are equal. ### Final Conclusion After analyzing all the given molecules, we find that only SiF4 has all equal bonds. Therefore, the answer to the question is: **Answer**: SiF4 ---

To determine which of the given molecules or ions has all equal bonds, we will analyze each option step by step. ### Step 1: Analyze SiF4 - **Structure**: SiF4 (Silicon Tetrafluoride) is a tetrahedral molecule. - **Hybridization**: The hybridization can be calculated as follows: - Silicon (Si) has 4 valence electrons. - There are 4 fluorine (F) atoms, each contributing 1 electron. - Total = 4 (Si) + 4 (F) = 8 electrons. ...
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