Home
Class 12
CHEMISTRY
Benzene reacts with CH(3)Cl in the prese...

Benzene reacts with `CH_(3)Cl` in the presence of anyhydrous `AlCl_(3)` to form

A

Toluene

B

Chlorobenzene

C

Benzylchloride

D

Xylene

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of what is formed when benzene reacts with CH₃Cl in the presence of anhydrous AlCl₃, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are benzene (C₆H₆) and methyl chloride (CH₃Cl). The presence of anhydrous aluminum chloride (AlCl₃) is crucial as it acts as a catalyst. ### Step 2: Understand the Reaction Type This reaction is a Friedel-Crafts alkylation. In this type of reaction, an alkyl group is introduced into the aromatic ring. The AlCl₃ catalyst helps in generating a more reactive species from CH₃Cl. ### Step 3: Formation of the Carbocation When CH₃Cl reacts with AlCl₃, it forms a methyl cation (CH₃⁺) and AlCl₄⁻. The AlCl₃ coordinates with the chlorine atom in CH₃Cl, facilitating the departure of Cl⁻ and generating the methyl cation. ### Step 4: Electrophilic Attack The methyl cation (CH₃⁺) is a strong electrophile. It will attack the benzene ring (C₆H₆) in an electrophilic substitution reaction. The π electrons of the benzene ring will attack the methyl cation, leading to the formation of a new carbon-carbon bond. ### Step 5: Formation of the Product After the electrophilic attack, a proton (H⁺) is lost from the benzene ring, restoring the aromaticity of the ring. The final product of this reaction is toluene (C₇H₈), which has a methyl group attached to the benzene ring. ### Conclusion Thus, the product formed when benzene reacts with CH₃Cl in the presence of anhydrous AlCl₃ is **toluene (C₇H₈)**. ---

To solve the question of what is formed when benzene reacts with CH₃Cl in the presence of anhydrous AlCl₃, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are benzene (C₆H₆) and methyl chloride (CH₃Cl). The presence of anhydrous aluminum chloride (AlCl₃) is crucial as it acts as a catalyst. ### Step 2: Understand the Reaction Type This reaction is a Friedel-Crafts alkylation. In this type of reaction, an alkyl group is introduced into the aromatic ring. The AlCl₃ catalyst helps in generating a more reactive species from CH₃Cl. ...
Promotional Banner

Topper's Solved these Questions

  • HYDROCARBON

    RESONANCE ENGLISH|Exercise INORGANIC CHEMISTRY (COORDINATION COMPOUNDS)|7 Videos
  • GASEOUS STATE

    RESONANCE ENGLISH|Exercise Exercise-3|1 Videos
  • IONIC EQUILIBRIUM

    RESONANCE ENGLISH|Exercise partIII one or more than one options correct type|10 Videos

Similar Questions

Explore conceptually related problems

Benzene reacts with CH_(3)COCl in the presence of anhy AlCl_(3) to give

Benzene reacts with n-propyl chloride in the presence of anhydrous AlCl_(3) to give predominantly

How does benzene react with, C_(2)H_(5)Cl in the presence of AlCl_(3)

The reaction of compounf P with CH_(3)MgBr (excess) in (C_(2)H_(5)_(2)O followed by addition of H_(2)O give Q the compound Q on treatment with H_(2)SO_(4) at 0^(@) C gives R. the reaction of R with CH_(3) COCl in the presence of anhydrous AlCl_(3)"in" CH_(2)Cl_(2) followed by treatment with H_(2)O produces compound S. [Et in compound P is ethyl group] The product S is

The reaction of compounf P with CH_(3)MgBr (excess) in (C_(2)H_(5)_(2)O followed by addition of H_(2)O give Q the compound Q on treatment with H_(2)SO_(4) at 0^(@) C gives R. the reaaction of R with CH_(3) COCl in the presence of anhydrous AlCl_(3) in CH_(2)Cl_(2) followed by treatment with H_(2)O "produces compound S . [Et in compound P is ethyl group] The reaction, Q to R and R TO S, are

Which of the following structures correspond to the product expected, when excess of C_(6)H_(6) reacts with CH_(2)Cl_(2) in presence of anhydrous AlCl_(3) .

Friedel-Crafts alkylation is expected to proceed through carbocationic intermediate. What would be the alkylation products when Benzene reacts with cyclopropyl chloride under the presence of anhydrous AlCl_(3) ?

What happens when benzene is treated with acetyl chloride in the presence of anhydrous AlCl_3

Name the electrophile produced in the reaction of benzene with benzoyl chloride in the presence of anhydrous AlCl_(3) . Name the reaction also.

RESONANCE ENGLISH-HYDROCARBON-ORGANIC CHEMISTRY(Hydrocarbon)
  1. Structural formula for lewisite is

    Text Solution

    |

  2. Acetylene react with alkaline KMnO(4) to give

    Text Solution

    |

  3. Benzene reacts with CH(3)Cl in the presence of anyhydrous AlCl(3) to f...

    Text Solution

    |

  4. Petroleum mainly contains :

    Text Solution

    |

  5. Which one of the following is most reactive towards electrophillic rea...

    Text Solution

    |

  6. CH3C-=C CH3underset(CaCO3 and BaSO4)overset((H2)/(Pd))to P Identifty t...

    Text Solution

    |

  7. The alkyl halides that can be made by free radical halogenation of alk...

    Text Solution

    |

  8. The species which acts as electrophile in the bromination of benzene...

    Text Solution

    |

  9. Reaction by which benzaldehyde cannot be prepared?

    Text Solution

    |

  10. Which of the following carbides on treatment with water give methane ...

    Text Solution

    |

  11. Propene, CH(3)-CH = CH(2), can be converted to 1-propanol by oxidation...

    Text Solution

    |

  12. What products are formed when the following compound is treated with ...

    Text Solution

    |

  13. When HCl gas is passed through propene in the presence of benzoyl pero...

    Text Solution

    |

  14. What is the energy in joule of photon of light whose wave length is 1....

    Text Solution

    |

  15. The treatment of benzene with isobutene in the presence of sulphuric a...

    Text Solution

    |

  16. The product 'Y' in the following reaction sequence is :

    Text Solution

    |

  17. Which of the following has the higest knocking property ?

    Text Solution

    |

  18. C(6)H(5)Cl+CH(3)Cloverset(Na//"dry ether")rarrC(6)H(5)CH(3)+2NaCl Th...

    Text Solution

    |

  19. The reaction CH(3)COCH(3)underset((ii)KOH,"glycol")overset((i)NH(2)-NH...

    Text Solution

    |

  20. Type of reactions shown by alkynes are -

    Text Solution

    |