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Using corey - house synthesis we can't p...

Using corey - house synthesis we can't prepare `…………………..` from ethylbromide.

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To solve the question regarding which compound cannot be prepared from ethyl bromide using the Corey-House synthesis, we will follow these steps: ### Step 1: Understand Corey-House Synthesis Corey-House synthesis involves the reaction of an alkyl halide (like ethyl bromide) with a dialkyl lithium cuprate (R2CuLi). The alkyl halide acts as an electrophile, while the dialkyl lithium cuprate acts as a nucleophile. The reaction proceeds via an SN2 mechanism, resulting in the formation of a new carbon-carbon bond. ### Step 2: Identify the Structure of Ethyl Bromide Ethyl bromide (C2H5Br) can be represented as: - R = C2H5 (ethyl group) - R' = the other alkyl group that will be added to form the final product. ### Step 3: Analyze Possible Products We need to analyze the given options (A, B, C, D) to determine which compound cannot be formed from ethyl bromide. Each compound can be represented as R-R', where R is the ethyl group (C2H5) and R' is another alkyl group. 1. **Option A**: If the compound can be broken down into an ethyl part and another alkyl part, it can be synthesized. 2. **Option B**: Similar to option A, if it can be broken down into ethyl and another alkyl part, it can be synthesized. 3. **Option C**: If the compound cannot be broken down into an ethyl part and another alkyl part, it cannot be synthesized from ethyl bromide. 4. **Option D**: If it can be broken down into ethyl and another alkyl part, it can be synthesized. ### Step 4: Determine the Correct Answer After analyzing the options: - **Option C** is the one that cannot be synthesized from ethyl bromide because it cannot be broken down into an ethyl part and another alkyl part. ### Conclusion The compound that cannot be prepared from ethyl bromide using Corey-House synthesis is **Option C**. ---

To solve the question regarding which compound cannot be prepared from ethyl bromide using the Corey-House synthesis, we will follow these steps: ### Step 1: Understand Corey-House Synthesis Corey-House synthesis involves the reaction of an alkyl halide (like ethyl bromide) with a dialkyl lithium cuprate (R2CuLi). The alkyl halide acts as an electrophile, while the dialkyl lithium cuprate acts as a nucleophile. The reaction proceeds via an SN2 mechanism, resulting in the formation of a new carbon-carbon bond. ### Step 2: Identify the Structure of Ethyl Bromide Ethyl bromide (C2H5Br) can be represented as: - R = C2H5 (ethyl group) ...
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Knowledge Check

  • Williamson synthesis is used to prepare

    A
    Alcohols
    B
    Ethers
    C
    Ketones
    D
    Aldehydes
  • Acetylene can be prepared from

    A
    potassium fumerate
    B
    calcium carbide
    C
    ethylene bromide
    D
    all of these.
  • Propanone can be prepared from ethyne by

    A
    passing a mixture of ethyne and steam over a catalyst, magnesium at `420^(@)C`
    B
    passing a mixture of ethyne and ethanol over a catalyst zinc chromite
    C
    boiling ethyne with water and `H_(2)SO_(4)`
    D
    treating ethyne with lodine and NaOH.
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