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Propene, CH(3)-CH = CH(2), can be conver...

Propene, `CH_(3)-CH = CH_(2)`, can be converted to `1`-propanol by oxidation. Which set of reagents among the following is ideal to
effect the conversion?

A

`KMnO_(4)("alkaline")`

B

Osmium tetraoxide `(OsO_(4)//CH_(2)Cl_(2))`

C

`B_(2)H_(6)` and alk. `H_(2)O_(2)`

D

`O_(3)//Zn`

Text Solution

AI Generated Solution

The correct Answer is:
To convert propene (CH₃-CH=CH₂) to 1-propanol (CH₃-CH₂-CH₂OH), we need to choose the appropriate reagents for oxidation. The ideal reagents for this conversion are those that will selectively add an -OH group to the terminal carbon of propene while following the anti-Markovnikov rule. ### Step-by-Step Solution: 1. **Identify the Structure of Propene and 1-Propanol**: - Propene has the structure CH₃-CH=CH₂. - 1-Propanol has the structure CH₃-CH₂-CH₂OH. 2. **Determine the Type of Reaction Needed**: - We need to perform an oxidation reaction that adds an -OH group to the terminal carbon of propene, resulting in 1-propanol. 3. **Select the Reagents**: - The best method for this transformation is hydroboration-oxidation. The hydroboration step will add a boron atom to the less substituted carbon (the terminal carbon), and the subsequent oxidation step will replace the boron with an -OH group. 4. **Reagents for Hydroboration-Oxidation**: - The reagents typically used are: - **BH₃ (Boron Hydride)** for hydroboration. - **H₂O₂ (Hydrogen Peroxide)** in the presence of a base (often NaOH) for oxidation. 5. **Reaction Mechanism**: - **Hydroboration**: The boron atom adds to the less substituted carbon of propene (the terminal carbon). - **Oxidation**: The boron is replaced by an -OH group, resulting in the formation of 1-propanol. 6. **Conclusion**: - The ideal set of reagents for converting propene to 1-propanol is **BH₃ followed by H₂O₂/NaOH**. ### Final Answer: The ideal set of reagents to convert propene to 1-propanol is **BH₃ followed by H₂O₂/NaOH**.

To convert propene (CH₃-CH=CH₂) to 1-propanol (CH₃-CH₂-CH₂OH), we need to choose the appropriate reagents for oxidation. The ideal reagents for this conversion are those that will selectively add an -OH group to the terminal carbon of propene while following the anti-Markovnikov rule. ### Step-by-Step Solution: 1. **Identify the Structure of Propene and 1-Propanol**: - Propene has the structure CH₃-CH=CH₂. - 1-Propanol has the structure CH₃-CH₂-CH₂OH. ...
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RESONANCE ENGLISH-HYDROCARBON-ORGANIC CHEMISTRY(Hydrocarbon)
  1. Reaction by which benzaldehyde cannot be prepared?

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  2. Which of the following carbides on treatment with water give methane ...

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  3. Propene, CH(3)-CH = CH(2), can be converted to 1-propanol by oxidation...

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  4. What products are formed when the following compound is treated with ...

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  5. When HCl gas is passed through propene in the presence of benzoyl pero...

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  6. What is the energy in joule of photon of light whose wave length is 1....

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  7. The treatment of benzene with isobutene in the presence of sulphuric a...

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  8. The product 'Y' in the following reaction sequence is :

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  9. Which of the following has the higest knocking property ?

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  10. C(6)H(5)Cl+CH(3)Cloverset(Na//"dry ether")rarrC(6)H(5)CH(3)+2NaCl Th...

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  11. The reaction CH(3)COCH(3)underset((ii)KOH,"glycol")overset((i)NH(2)-NH...

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  12. Type of reactions shown by alkynes are -

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  13. Which of the following produces one mononitro and three isomeric dinit...

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  14. The threshold wavelength for ejection of electrons from a metal is 230...

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  15. The reaction of HBr with gives

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  16. In which of the following Hoffmann elimination product is more ?

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  17. Which of the following is not aromatic?

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  18. Identify Z in the series CH(3)CH(2)CH(2)OHunderset(160-180^(@)C)over...

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  19. In the reaction, product 'X' is : CH(3)-C=CH+H(2)Ooverset(H^(+)//Hg^...

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  20. For the given reaction how many monochloro products are optically acti...

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