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When HCl gas is passed through propene i...

When `HCl` gas is passed through propene in the presence of benzoyl peroxide, it gives `:`

A

`2-` chloropropane

B

Allyl chloride

C

No reaction

D

`n-` propyl chloride

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To solve the question of what product is formed when HCl gas is passed through propene in the presence of benzoyl peroxide, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are propene (C3H6) and hydrogen chloride (HCl). The presence of benzoyl peroxide is also noted, which is a radical initiator. 2. **Understand the Reaction Mechanism**: When HCl reacts with alkenes, the addition of HCl typically follows Markovnikov's rule. However, in the presence of benzoyl peroxide, the reaction can lead to anti-Markovnikov addition due to the formation of free radicals. However, in this specific case, the reaction with HCl does not follow the radical pathway. 3. **Apply Markovnikov's Rule**: According to Markovnikov's rule, the hydrogen atom (H+) from HCl will attach to the carbon atom of the double bond that has more hydrogen atoms, while the chlorine atom (Cl-) will attach to the carbon atom with fewer hydrogen atoms. - Propene has the structure: \[ CH_3-CH=CH_2 \] - The carbon atoms involved in the double bond are: - Carbon 1 (CH2) has 2 hydrogen atoms. - Carbon 2 (CH) has 1 hydrogen atom. 4. **Determine the Product**: Based on Markovnikov's rule: - H+ will attach to Carbon 1 (CH2), and Cl- will attach to Carbon 2 (CH). - This results in the formation of 2-chloropropane: \[ CH_3-CHCl-CH_3 \] 5. **Final Product**: The final product of the reaction when HCl is passed through propene in the presence of benzoyl peroxide is 2-chloropropane. ### Conclusion: The product formed is **2-chloropropane**. ---

To solve the question of what product is formed when HCl gas is passed through propene in the presence of benzoyl peroxide, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are propene (C3H6) and hydrogen chloride (HCl). The presence of benzoyl peroxide is also noted, which is a radical initiator. 2. **Understand the Reaction Mechanism**: When HCl reacts with alkenes, the addition of HCl typically follows Markovnikov's rule. However, in the presence of benzoyl peroxide, the reaction can lead to anti-Markovnikov addition due to the formation of free radicals. However, in this specific case, the reaction with HCl does not follow the radical pathway. ...
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RESONANCE ENGLISH-HYDROCARBON-ORGANIC CHEMISTRY(Hydrocarbon)
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