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Identify Z in the series CH(3)CH(2)CH(...

Identify Z in the series
`CH_(3)CH_(2)CH_(2)OHunderset(160-180^(@)C)overset(conc.H_(2)SO_(4))rarr(X)overset(Br_(2))rarr(Y)underset(NaNH_(2)//Delta)overset(alc,KOH//Delta)rarr(Z)`

A

`CH_(3)-underset(underset(OH)|)(CH)-underset(underset(OH)|)(CH_(2))`

B

`CH_(3)CH_(2)CH(OH)_(2)`

C

`CH_(3)-underset(underset(OH)|)(C)=CH_(2)`

D

`CH_(3)-C=CH`

Text Solution

AI Generated Solution

The correct Answer is:
To identify the compound Z in the given reaction series, we will analyze each step of the transformation starting from propanol (CH₃CH₂CH₂OH). ### Step 1: Dehydration of Propanol The first step involves heating propanol (CH₃CH₂CH₂OH) with concentrated sulfuric acid (H₂SO₄) at 160-180°C. This process leads to dehydration, where a water molecule is removed, resulting in the formation of an alkene. **Product after Step 1:** - The dehydration of propanol yields propene (CH₃CH=CH₂). ### Step 2: Electrophilic Addition with Br₂ Next, the alkene (propene) is treated with bromine (Br₂). This reaction is an electrophilic addition reaction, where bromine adds across the double bond. **Product after Step 2:** - The product of this reaction is 1,2-dibromopropane (CH₃CHBrCH₂Br). ### Step 3: Dehydrohalogenation with Alcoholic KOH The 1,2-dibromopropane is then treated with alcoholic potassium hydroxide (alc. KOH) under heating conditions. This step involves dehydrohalogenation, where hydrogen and bromine are removed, resulting in the formation of another alkene. **Product after Step 3:** - The product formed is 1-bromo-1-propene (CH₃C=CHBr). ### Step 4: Reaction with NaNH₂ Finally, the compound (1-bromo-1-propene) is treated with sodium amide (NaNH₂), which is a strong base. This step leads to the elimination of the bromine atom and the formation of a triple bond. **Product after Step 4:** - The final product is propyne (CH≡C-CH₃). ### Final Answer Thus, the compound Z in the series is propyne (CH≡C-CH₃). ---

To identify the compound Z in the given reaction series, we will analyze each step of the transformation starting from propanol (CH₃CH₂CH₂OH). ### Step 1: Dehydration of Propanol The first step involves heating propanol (CH₃CH₂CH₂OH) with concentrated sulfuric acid (H₂SO₄) at 160-180°C. This process leads to dehydration, where a water molecule is removed, resulting in the formation of an alkene. **Product after Step 1:** - The dehydration of propanol yields propene (CH₃CH=CH₂). ...
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