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If two liquids A(P(A)^(@)=100 torr) and ...

If two liquids `A(P_(A)^(@)=100` torr) and `B(P_(B)^(@)=200` torr) are completely immiscible with each other, each one will behave independently of the other, are present in a closed vessel. The total vapour pressure of the system will be:

A

less than `100` torr

B

greater than `200` torr

C

between `100` to `200` torr

D

`300` torr

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The correct Answer is:
To solve the problem of calculating the total vapor pressure of two immiscible liquids A and B in a closed vessel, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Given Data**: - Vapor pressure of liquid A, \( P_{A}^{(@)} = 100 \) torr - Vapor pressure of liquid B, \( P_{B}^{(@)} = 200 \) torr 2. **Understand the Concept of Immiscible Liquids**: - Immiscible liquids do not mix and each liquid exerts its own vapor pressure independently in the closed system. 3. **Apply Raoult's Law for Total Vapor Pressure**: - According to Raoult's Law, the total vapor pressure \( P_{total} \) for a system of two immiscible liquids is the sum of the vapor pressures of the individual liquids: \[ P_{total} = P_{A}^{(@)} + P_{B}^{(@)} \] 4. **Substitute the Values**: - Substitute the given vapor pressures into the equation: \[ P_{total} = 100 \, \text{torr} + 200 \, \text{torr} \] 5. **Calculate the Total Vapor Pressure**: - Perform the addition: \[ P_{total} = 300 \, \text{torr} \] 6. **Conclusion**: - The total vapor pressure of the system is \( 300 \) torr. ### Final Answer: The total vapor pressure of the system is \( 300 \) torr. ---
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