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For the given electrolyte A(x)B(y). The ...

For the given electrolyte `A_(x)B_(y)`. The degree of dissociation `'alpha'` can be given as:

A

`alpha=(i-1)/(x+y-1)`

B

`i=(1-alpha)+xalpha+yalpha`

C

`alpha=(1-i)/(1-x-y)`

D

none

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The correct Answer is:
To find the degree of dissociation (α) for the electrolyte \( A_xB_y \), we can follow these steps: ### Step 1: Understand the dissociation of the electrolyte The electrolyte \( A_xB_y \) dissociates in solution to form \( x \) moles of \( A \) and \( y \) moles of \( B \). The dissociation can be represented as: \[ A_xB_y \rightleftharpoons xA + yB \] ### Step 2: Define the degree of dissociation Let \( \alpha \) be the degree of dissociation. This means that if we start with 1 mole of \( A_xB_y \), after dissociation, \( \alpha \) moles of \( A_xB_y \) will dissociate. ### Step 3: Calculate the moles after dissociation Initially, we have: - 1 mole of \( A_xB_y \) - After dissociation, the moles of \( A \) formed will be \( x\alpha \) and the moles of \( B \) formed will be \( y\alpha \). Thus, the total number of moles after dissociation can be expressed as: \[ \text{Total moles} = 1 - \alpha + x\alpha + y\alpha = 1 + (x + y - 1)\alpha \] ### Step 4: Calculate the van 't Hoff factor (i) The van 't Hoff factor \( i \) is defined as the total number of particles in solution after dissociation. Therefore, we have: \[ i = \text{Total moles after dissociation} = 1 + (x + y - 1)\alpha \] ### Step 5: Relate degree of dissociation to van 't Hoff factor From the expression for \( i \): \[ i = 1 + (x + y - 1)\alpha \] Rearranging gives: \[ \alpha = \frac{i - 1}{x + y - 1} \] ### Step 6: Alternative expression for degree of dissociation We can also express \( i \) in terms of \( \alpha \): \[ i = 1 - \alpha + x\alpha + y\alpha = 1 + (x + y - 1)\alpha \] ### Final Expression for Degree of Dissociation Thus, we can conclude that the degree of dissociation \( \alpha \) can be expressed as: \[ \alpha = \frac{i - 1}{x + y - 1} \] or alternatively, \[ \alpha = \frac{1 - i}{1 - (x + y)} \] ### Conclusion The degree of dissociation \( \alpha \) for the electrolyte \( A_xB_y \) can be expressed using the above equations, indicating that all forms provided in the options can be correct depending on the context.

To find the degree of dissociation (α) for the electrolyte \( A_xB_y \), we can follow these steps: ### Step 1: Understand the dissociation of the electrolyte The electrolyte \( A_xB_y \) dissociates in solution to form \( x \) moles of \( A \) and \( y \) moles of \( B \). The dissociation can be represented as: \[ A_xB_y \rightleftharpoons xA + yB \] ...
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