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The concept of resonance explains variou...

The concept of resonance explains various properties of compounds.The molecules with conjugated system of `pi` bonds, are stabilized by resonace and have low heat of hydrogenation.Hyperconjugative stabilization also decreases heat f hydrogenation.In aromic rings a functional group with a lone pair of electron exerts +m effect. Some functional groups like -NO, -NC, -CH=`CH_2` can function both as electron releasing (+m,+R) or electron withdrawing (-m,-R) groups.More extended conjugation provides more stabilization.
The correct heat of hydrogenation order is
(p)1,3-Pentadiene , (q)1,3-Butadiene , (r)2,3-Dimethyl-1,3-butadiene , (s)Propadiene

A

pgtqgtrgts

B

sgtqgtpgtr

C

qgtsgtpgtr

D

sgtpgtqgtr

Text Solution

Verified by Experts

The correct Answer is:
B

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A compound having one lone pair of electrons :

Compound 'A' has many functional groups.

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Hydrogenation of unsaturated hydrocarbons is an exothermic reaction. Due to hyperconjugation and resonance the stability of unsaturated hydrocarbons increases and the increase in stability is more due to resonance. Compound with same number of pi- bonds and more stability has lower heat of hydrogenation. Heat of formation is defined as the energy evolved when a molecule is formed from its atoms. For isomers the more stable compounds has higher heat of formation. The correct heat of hydrogenation order is : (p) 1,3-Pentadiene (q) 1,3-Butadiene (r) 2,3-Dimethyl-1,3-butadiene (s) Propadiene

Name the functional group of each of CH_3OH, CH_3COOH and CH_3 CHO

Which functional group is present in a molecule of CH_3OH ?

What is the functional group present in the CH_3COOH

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