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Preparation of organosilicones from SiCl...

Preparation of organosilicones from `SiCl_(4)` involves substituion in first step:
`SiCl_(4)+xRMgCl to (R)_(x) SiCl_(4-x)+xMgCl_(2)`
Values of 'x' to obtain chain terminating & chain multiplication parts of chain silicone produced are respectively:

A

1&2

B

2&1

C

2&3

D

3&2

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the preparation of organosilicones from SiCl₄, we need to analyze the reaction and determine the values of 'x' for chain terminating and chain multiplication parts of the silicone produced. ### Step-by-Step Solution: 1. **Understand the Reaction**: The reaction given is: \[ \text{SiCl}_4 + x \text{RMgCl} \rightarrow (R)_x \text{SiCl}_{4-x} + x \text{MgCl}_2 \] Here, SiCl₄ (silicon tetrachloride) reacts with x moles of RMgCl (an organomagnesium compound). 2. **Identify the Products**: The products of this reaction are: - \( (R)_x \text{SiCl}_{4-x} \): This represents an organosilicone compound where 'R' groups are attached to silicon. - \( x \text{MgCl}_2 \): This is magnesium dichloride. 3. **Determine Chain Termination and Chain Multiplication**: - **Chain Terminating Part**: This part of the silicone structure will have 3 R groups attached to silicon and one chlorine atom remaining. This means that for the chain terminating part, we have: \[ \text{Si} \text{(R)}_3 \text{Cl} \] Here, the value of x for the chain terminating part is 3 (since there are 3 R groups). - **Chain Multiplication Part**: This part will have 2 R groups attached to silicon and 2 chlorine atoms remaining. This means that for the chain multiplication part, we have: \[ \text{Si} \text{(R)}_2 \text{Cl}_2 \] Here, the value of x for the chain multiplication part is 2 (since there are 2 R groups). 4. **Final Values**: Therefore, the values of 'x' for the chain terminating and chain multiplication parts of the silicone produced are: - Chain Terminating: x = 3 - Chain Multiplication: x = 2 ### Conclusion: The final answer is: - For chain terminating part: **3** - For chain multiplication part: **2**

To solve the question regarding the preparation of organosilicones from SiCl₄, we need to analyze the reaction and determine the values of 'x' for chain terminating and chain multiplication parts of the silicone produced. ### Step-by-Step Solution: 1. **Understand the Reaction**: The reaction given is: \[ \text{SiCl}_4 + x \text{RMgCl} \rightarrow (R)_x \text{SiCl}_{4-x} + x \text{MgCl}_2 ...
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