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4BCl(3)+ 3LiAIH(4) to A+ 3AlCl(3)+3 LiCl...

`4BCl_(3)+ 3LiAIH_(4) to A+ 3AlCl_(3)+3 LiCl`
When `A` reacts with `NaOH` it produces a colourless combustible gas and another compound 'B'. Select incorrect statement about 'B'

A

(1) It aqueous solution turns red litmus blue

B

It shows anionic hydrolysis

C

It shows cationic hydrolysis

D

It can also produce by reaction of boron with NaOH

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to follow these steps: ### Step 1: Identify Compound A The reaction given is: \[ 4BCl_3 + 3LiAlH_4 \rightarrow A + 3AlCl_3 + 3LiCl \] Here, \( A \) is formed when boron trichloride reacts with lithium aluminum hydride. The product of this reaction is diborane (\( B_2H_6 \)). So, we can write: \[ A = B_2H_6 \] ### Step 2: Determine the Reaction of A with NaOH Next, we need to analyze the reaction of \( A \) (diborane) with sodium hydroxide (\( NaOH \)): \[ B_2H_6 + NaOH \rightarrow B + \text{(colorless combustible gas)} \] When diborane reacts with sodium hydroxide, it produces sodium borate (\( Na_3BO_3 \)) and hydrogen gas (\( H_2 \)), which is the colorless combustible gas. ### Step 3: Identify Compound B From the reaction, we can conclude: \[ B = Na_3BO_3 \] ### Step 4: Analyze the Properties of Compound B Now, we need to evaluate the statements regarding \( B \) (sodium borate, \( Na_3BO_3 \)) to find the incorrect one. 1. **Statement 1**: "Its aqua solution turns red litmus blue." - This is correct because sodium borate is a basic salt and will turn red litmus paper blue. 2. **Statement 2**: "It shows anionic hydrolysis." - This is also correct. Sodium borate undergoes anionic hydrolysis because it is a salt of a strong base (NaOH) and a weak acid (Boric acid). 3. **Statement 3**: "It shows cationic hydrolysis." - This statement is incorrect. Cationic hydrolysis occurs in salts formed from strong acids and weak bases, which is not the case here. 4. **Statement 4**: "It can also be produced by the reaction of boron with NaOH." - This is correct. Sodium borate can indeed be formed from the reaction of boron with sodium hydroxide. ### Conclusion The incorrect statement about compound \( B \) (sodium borate) is: **"It shows cationic hydrolysis."**

To solve the question, we need to follow these steps: ### Step 1: Identify Compound A The reaction given is: \[ 4BCl_3 + 3LiAlH_4 \rightarrow A + 3AlCl_3 + 3LiCl \] Here, \( A \) is formed when boron trichloride reacts with lithium aluminum hydride. The product of this reaction is diborane (\( B_2H_6 \)). ...
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RESONANCE ENGLISH-P-BLOCK ELEMENT (BORON AND CARBON FAMILY)-Advanced Level Problems Part-I : PRACTICE TEST-1 (IIT-JEE (MAIN Pattern))
  1. Which of the following statement about Si is correct.

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  2. Identify correct statement.

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  3. 4BCl(3)+ 3LiAIH(4) to A+ 3AlCl(3)+3 LiCl When A reacts with NaOH it...

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  4. When heating white lead then find out released gas (A) and (B) under...

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  5. Amorphous boron is extracted from borax by the following steps : "Bo...

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  6. The role of addition of Me(3)SiCl during the hydrolysis followed by co...

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  7. Given type of silicones are called [P] -O-oversetoverset(R)(|)unders...

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  8. Which of the following is not a property of silicones ?

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  9. Tourmalene is a class of cyclosilicates with general formula. (Ca, K...

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  10. The silicate anion in the mineral kinoite is a chain of three SiO(4) t...

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  11. The dehydration of malonic acid CH(2) (COOH)(2) with P(4)O(10) and hea...

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  12. Borax on heating with cobalt oxide forms a blue bead of

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  13. The dissolution of Al(OH)(3) by a solution of NaOH results in the form...

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  14. Select the incorrect statement about the boron.

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  15. Aqueous solution containing 1 mol of borax raects with 2 mol of acids....

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  16. Water transpoted through Lead pipes becomes poisonous due to the forma...

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  17. When a mixture of air and steam is passed over red hot coke, the outgo...

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  18. In BF(3), the B-F bond length is 1.30 A, when BF(3) is allowed to be t...

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  19. Aluminium is extracted in the electrolysis of :

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  20. A compound X, of boron reacts with NH(3) on heating to give another co...

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