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Amorphous boron is extracted from borax ...

Amorphous boron is extracted from borax by the following steps :
`"Borax" overset((A))rarr H_(3) BO_(3) overset("Heat")rarr B_(2) O_(3) overset((B)) rarr "Boron" (A) and (B) are`
(a) `H_(2) SO_(4), Al`
(b) `HCl`, Carbon
( c) `H_(2) SO_(4), Mg`
(d) `HCl, Fe`.

A

`H_(2)SO_(4),Al`

B

`HCl`,carbon

C

`H_(2)SO_(4),Mg`

D

`HCl,Fe`

Text Solution

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The correct Answer is:
To solve the question regarding the extraction of amorphous boron from borax, we will break down the process step by step. ### Step 1: Understand the Starting Material - **Borax** is a compound with the formula \( \text{Na}_2\text{B}_4\text{O}_7 \). It is the starting material for the extraction of boron. ### Step 2: Identify the First Reaction - The first step involves the reaction of borax with an acid to form boric acid. - When borax is treated with concentrated sulfuric acid (\( \text{H}_2\text{SO}_4 \)), it produces boric acid (\( \text{H}_3\text{BO}_3 \)) and sodium sulfate (\( \text{Na}_2\text{SO}_4 \)). - The balanced reaction can be represented as: \[ \text{Na}_2\text{B}_4\text{O}_7 + 5 \text{H}_2\text{SO}_4 + 5 \text{H}_2\text{O} \rightarrow \text{Na}_2\text{SO}_4 + 4 \text{H}_3\text{BO}_3 \] - Thus, **A** in the reaction is \( \text{H}_2\text{SO}_4 \). ### Step 3: Identify the Second Reaction - The second step involves heating boric acid to produce boron oxide (\( \text{B}_2\text{O}_3 \)). - When boric acid is heated, it loses water and forms boron oxide: \[ 2 \text{H}_3\text{BO}_3 \xrightarrow{\text{Heat}} \text{B}_2\text{O}_3 + 3 \text{H}_2\text{O} \] ### Step 4: Identify the Final Reaction - The final step involves reducing boron oxide (\( \text{B}_2\text{O}_3 \)) to obtain boron. - This reduction can be achieved using magnesium (\( \text{Mg} \)), which is a strong reducing agent: \[ \text{B}_2\text{O}_3 + 3 \text{Mg} \rightarrow 2 \text{B} + 3 \text{MgO} \] - Thus, **B** in the reaction is \( \text{Mg} \). ### Conclusion - Therefore, the correct answer for the unknowns A and B is: - (A) \( \text{H}_2\text{SO}_4 \) - (B) \( \text{Mg} \) The correct option is (c) \( \text{H}_2\text{SO}_4, \text{Mg} \).

To solve the question regarding the extraction of amorphous boron from borax, we will break down the process step by step. ### Step 1: Understand the Starting Material - **Borax** is a compound with the formula \( \text{Na}_2\text{B}_4\text{O}_7 \). It is the starting material for the extraction of boron. ### Step 2: Identify the First Reaction - The first step involves the reaction of borax with an acid to form boric acid. - When borax is treated with concentrated sulfuric acid (\( \text{H}_2\text{SO}_4 \)), it produces boric acid (\( \text{H}_3\text{BO}_3 \)) and sodium sulfate (\( \text{Na}_2\text{SO}_4 \)). ...
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