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(i)P+C("carbon")+Cl(2)toQ+CO uarr , (ii)...

(i)`P+C("carbon")+Cl_(2)toQ+CO uarr` , (ii)`Q+H_(2)OtoR+HCl`
(iii)`BN+H_(2)O to R+NH_(3)` , (iv)`Q+LiAIH_(4) to S+LiCl+ AlCl_(3)`
(v)`S+H_(2)toR+H_(2) uarr` , (vi)`S+NaH to T`
(`P,Q,R,S` and `T` do not represent their chemical symbols)
Compound S is

A

Sodium borohydride

B

Boron trichloride

C

Orthoboric acid

D

diborane

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze each reaction and identify the compounds involved. ### Step 1: Identify Compound P The first reaction is: \[ P + C + Cl_2 \rightarrow Q + CO \] From the context, we can deduce that compound P is likely **Boric Oxide (B2O3)**. This is because boron compounds typically react with carbon and chlorine to form boron trichloride (Q) and carbon monoxide. ### Step 2: Identify Compound Q Using the information from Step 1, we can conclude that: \[ Q = BCl_3 \] (Boron Trichloride) ### Step 3: Identify Compound R The second reaction is: \[ Q + H_2O \rightarrow R + HCl \] When boron trichloride (BCl3) reacts with water, it undergoes hydrolysis to form **Ortho Boric Acid (H3BO3)**. Therefore: \[ R = H3BO3 \] ### Step 4: Analyze the Third Reaction The third reaction is: \[ BN + H_2O \rightarrow R + NH_3 \] Boron nitride (BN) reacts with water to produce ortho boric acid (R) and ammonia (NH3). This confirms that R is indeed **H3BO3**. ### Step 5: Identify Compound S The fourth reaction is: \[ Q + LiAlH_4 \rightarrow S + LiCl + AlCl_3 \] When boron trichloride (BCl3) reacts with lithium aluminum hydride (LiAlH4), it forms **Diborane (B2H6)**. Thus: \[ S = B2H6 \] ### Step 6: Analyze the Fifth Reaction The fifth reaction is: \[ S + H_2 \rightarrow R + H_2 \] When diborane (B2H6) reacts with hydrogen, it produces ortho boric acid (R) and releases hydrogen gas. This confirms that R is **H3BO3**. ### Step 7: Analyze the Sixth Reaction The sixth reaction is: \[ S + NaH \rightarrow T \] When diborane (B2H6) reacts with sodium hydride (NaH), it forms **Sodium Borohydride (NaBH4)**, which is a common reducing agent. Therefore: \[ T = NaBH4 \] ### Conclusion After analyzing all the reactions, we conclude that the compound S is: \[ \text{Compound S is Diborane (B2H6)} \] ---

To solve the problem step by step, we will analyze each reaction and identify the compounds involved. ### Step 1: Identify Compound P The first reaction is: \[ P + C + Cl_2 \rightarrow Q + CO \] From the context, we can deduce that compound P is likely **Boric Oxide (B2O3)**. This is because boron compounds typically react with carbon and chlorine to form boron trichloride (Q) and carbon monoxide. ...
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