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In the reaction AB(2)(l)+3X(2)(g)hArrAX(...

In the reaction `AB_(2)(l)+3X_(2)(g)hArrAX_(2)(g)+2BX_(2)(g)+2BX_(2)(g)Delta H= -270` kcal per mol. of `AB_(2)(l)`.
the enthalpies of formation of `AX_(2)(g) & BX_(2)(g)` are in the ratio of `4:3` and have opposite sign. The value of `Delta H_(f)^(0)(AB_(2)(l))= +30` kcal/mol. Then

A

`DeltaH_(f)^(0)(AX_(2))= -96 kcal//mol`

B

`DeltaH_(f)^(0)(BX_(2))= +480 kcal//mol`

C

`K_(p)=K_(c) & Delta H_(f)^(0)(AX_(2))= + 480 kcal//mol`

D

`K_(p)=K_(c)RT & DeltaH_(f)^(0)(AX_(2))+DeltaH_(f)^(0)(BX_(2))= -240 kcal//mol`

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The correct Answer is:
To solve the problem, we need to analyze the given reaction and the information provided about the enthalpy changes and the enthalpies of formation. ### Step-by-Step Solution: 1. **Write the Reaction and Given Data:** The reaction is: \[ AB_2(l) + 3X_2(g) \rightleftharpoons AX_2(g) + 2BX_2(g) \] Given: - \(\Delta H = -270 \text{ kcal/mol of } AB_2\) - \(\Delta H_f(AB_2) = +30 \text{ kcal/mol}\) - The enthalpies of formation of \(AX_2\) and \(BX_2\) are in the ratio \(4:3\) and have opposite signs. 2. **Define Enthalpies of Formation:** Let: - \(\Delta H_f(AX_2) = 4x\) - \(\Delta H_f(BX_2) = -3x\) 3. **Set Up the Enthalpy Change Equation:** The enthalpy change for the reaction can be expressed as: \[ \Delta H = \Delta H_f(AX_2) + 2 \Delta H_f(BX_2) - \Delta H_f(AB_2) \] Substituting the values: \[ -270 = (4x) + 2(-3x) - 30 \] Simplifying this gives: \[ -270 = 4x - 6x - 30 \] \[ -270 = -2x - 30 \] 4. **Solve for \(x\):** Rearranging the equation: \[ -2x = -270 + 30 \] \[ -2x = -240 \] \[ x = 120 \] 5. **Calculate Enthalpies of Formation:** Now substitute \(x\) back to find the enthalpies of formation: \[ \Delta H_f(AX_2) = 4x = 4 \times 120 = 480 \text{ kcal/mol} \] \[ \Delta H_f(BX_2) = -3x = -3 \times 120 = -360 \text{ kcal/mol} \] 6. **Determine the Relationship Between \(K_p\) and \(K_c\):** Calculate \(\Delta N_g\) (the change in moles of gas): - Moles of gaseous products = \(1 (AX_2) + 2 (BX_2) = 3\) - Moles of gaseous reactants = \(3 (X_2)\) - Thus, \(\Delta N_g = 3 - 3 = 0\) Since \(\Delta N_g = 0\), we have: \[ K_p = K_c \cdot R^{\Delta N_g} = K_c \cdot R^0 = K_c \] 7. **Conclusion:** The correct options regarding the enthalpies of formation and the relationship between \(K_p\) and \(K_c\) are: - \(\Delta H_f(AX_2) = 480 \text{ kcal/mol}\) - \(\Delta H_f(BX_2) = -360 \text{ kcal/mol}\) - \(K_p = K_c\)

To solve the problem, we need to analyze the given reaction and the information provided about the enthalpy changes and the enthalpies of formation. ### Step-by-Step Solution: 1. **Write the Reaction and Given Data:** The reaction is: \[ AB_2(l) + 3X_2(g) \rightleftharpoons AX_2(g) + 2BX_2(g) ...
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