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Bond energies of N-=N, H-H and N-H bonds...

Bond energies of `N-=N, H-H` and `N-H` bonds are 945,463 & 391 kJ `mol^(-1)` respectively, the enthalpy of the following reactions is :
`N_(2)(g)+3H_(2)(g)rarr2NH_(3)(g)`

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To calculate the enthalpy change for the reaction: \[ N_2(g) + 3H_2(g) \rightarrow 2NH_3(g) \] we will use the bond energies provided for the bonds involved in the reaction. The bond energies are as follows: - Bond energy of \( N \equiv N \) (N triple bond N) = 945 kJ/mol - Bond energy of \( H-H \) = 463 kJ/mol - Bond energy of \( N-H \) = 391 kJ/mol ### Step-by-Step Solution: 1. **Identify Bonds Broken and Formed:** - In the reactants, we have: - 1 bond of \( N \equiv N \) (1 N2 molecule) - 3 bonds of \( H-H \) (3 H2 molecules) - In the products, we have: - 6 bonds of \( N-H \) (2 NH3 molecules, each containing 3 N-H bonds) 2. **Calculate the Total Energy of Bonds Broken:** - Energy required to break the bonds in the reactants: \[ \text{Total Energy of Bonds Broken} = \text{Energy of } N \equiv N + 3 \times \text{Energy of } H-H \] \[ = 945 \text{ kJ/mol} + 3 \times 463 \text{ kJ/mol} \] \[ = 945 + 1389 = 2334 \text{ kJ/mol} \] 3. **Calculate the Total Energy of Bonds Formed:** - Energy released when forming the bonds in the products: \[ \text{Total Energy of Bonds Formed} = 6 \times \text{Energy of } N-H \] \[ = 6 \times 391 \text{ kJ/mol} \] \[ = 2346 \text{ kJ/mol} \] 4. **Calculate the Enthalpy Change (\( \Delta H \)):** - The enthalpy change for the reaction is given by: \[ \Delta H = \text{Total Energy of Bonds Broken} - \text{Total Energy of Bonds Formed} \] \[ = 2334 \text{ kJ/mol} - 2346 \text{ kJ/mol} \] \[ = -12 \text{ kJ/mol} \] ### Final Answer: The enthalpy change (\( \Delta H \)) for the reaction \( N_2(g) + 3H_2(g) \rightarrow 2NH_3(g) \) is \(-12 \text{ kJ/mol}\).

To calculate the enthalpy change for the reaction: \[ N_2(g) + 3H_2(g) \rightarrow 2NH_3(g) \] we will use the bond energies provided for the bonds involved in the reaction. The bond energies are as follows: - Bond energy of \( N \equiv N \) (N triple bond N) = 945 kJ/mol - Bond energy of \( H-H \) = 463 kJ/mol ...
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