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For a cell given below: Ag|Ag^(+)||Cu^...

For a cell given below:
`Ag|Ag^(+)||Cu^(2+)|Cu`
`Ag^(+)+e^(-)toAg,E^(@)=x`
`Cu^(2+)+2e^(-)toCu,,E^(@)=y` ltbr. The value of `E_(cell)^(@)` is

A

`x+2y`

B

`2x+y`

C

`y-x`

D

`y-2x`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the standard cell potential \( E_{\text{cell}}^{\circ} \) for the electrochemical cell given by the half-reactions: 1. \( \text{Ag}^+ + e^- \rightarrow \text{Ag}, \quad E^{\circ} = x \) 2. \( \text{Cu}^{2+} + 2e^- \rightarrow \text{Cu}, \quad E^{\circ} = y \) ### Step-by-Step Solution: **Step 1: Identify the Anode and Cathode** - In the given cell notation \( \text{Ag} | \text{Ag}^+ || \text{Cu}^{2+} | \text{Cu} \), the left side represents the anode and the right side represents the cathode. - The anode is where oxidation occurs, and the cathode is where reduction occurs. **Step 2: Determine the Half-Reactions** - At the anode (oxidation): \[ \text{Ag} \rightarrow \text{Ag}^+ + e^- \] The standard reduction potential for this reaction is \( x \), but since it is oxidation, we take it as \( -x \). - At the cathode (reduction): \[ \text{Cu}^{2+} + 2e^- \rightarrow \text{Cu} \] The standard reduction potential for this reaction is \( y \). **Step 3: Write the Cell Potential Formula** - The standard cell potential \( E_{\text{cell}}^{\circ} \) can be calculated using the formula: \[ E_{\text{cell}}^{\circ} = E_{\text{cathode}}^{\circ} - E_{\text{anode}}^{\circ} \] **Step 4: Substitute the Values** - Substitute the values of the potentials into the formula: \[ E_{\text{cell}}^{\circ} = y - (-x) = y + x \] **Step 5: Final Result** - Therefore, the value of \( E_{\text{cell}}^{\circ} \) is: \[ E_{\text{cell}}^{\circ} = y + x \]

To solve the problem, we need to determine the standard cell potential \( E_{\text{cell}}^{\circ} \) for the electrochemical cell given by the half-reactions: 1. \( \text{Ag}^+ + e^- \rightarrow \text{Ag}, \quad E^{\circ} = x \) 2. \( \text{Cu}^{2+} + 2e^- \rightarrow \text{Cu}, \quad E^{\circ} = y \) ### Step-by-Step Solution: **Step 1: Identify the Anode and Cathode** ...
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E^@ values for the half cell reactions are given below : Cu^(2+) + e^(-) to Cu^(+) , E^@ =0.15 V Cu^(2+) + 2e^(-) to Cu, E^@ =0.34 V What will be the E^@ of the half-cell : Cu^(+) + e^(-) to Cu ?

The voltage of a cell whose half-cells are given below is Mg^(2+)+2e^(-)rarrMg(s),E^(@)=-2.37V Cu^(2+)+2e^(-)rarrCu(s),E^(@)=+0.34V standard EMF of the cell is

The standard potential E^(@) for the half reactions are as : Zn rarr Zn^(2+) + 2e^(-), E^(@) = 0.76V Cu rarr Cu^(2+) +2e^(-) , E^(@) = -0.34 V The standard cell voltage for the cell reaction is ? Zn +Cu^(2) rarr Zn ^(2+) +Cu

Find out the E_("cell")^(@) from the given data (a) Zn|Zn^(+2)|| Cu^(+2)| Cu, E_("cell")^(@) = 1.10V (b) Cu| Cu^(+2)|| Ag^(+)|Ag, E_("cell")^(@) = 0.46V ( c) Zn|Zn^(+2)||Ag^(+) | Ag, E_("cell")^(@) = ? (Given E_(Cu^(+2)//Cu)^(@) = 0.34V )

The e.m.f. ( E^(0) )of the following cells are Ag| Ag^(+)(1M) | | Cu^(2+)(1M) | Cu, E^(0) = -0.46V , Zn|Zn^(2+)(1M)| | Cu^(2+)(1M) | Cu : E^(0) = +1.10V Calculate the e.m.f. of the cell Zn | Zn^(2+)(1M) | | Ag^(+)(1M) | Ag

E_(Cu^(2+)//Cu)^(@)=0.34V E_(Cu^(+)//Cu)^(@)=0.522V E_(Cu^(2+)//Cu^(+))^(@)=

E_(Cu^(2+)//Cu)^(@)=0.34V E_(Cu^(+)//Cu)^(@)=0.522V E_(Cu^(2+)//Cu^(+))^(@)=

E_(Cu^(2+)//Cu)^(@) =0.43V E_(Cu^(+)//Cu)^(@)=0.55V E_(Cu^(2+)//Cu^(+))^(@) =

If E_(Cu^(2+)|Cu)^(@) = 0.34V and E_(Cu^(2+)|Cu^(+))^(@)= 0.15 V then the value for disproportion for Cu^(+) is :

The standard reducution potentials of Zn^(2+)|Zn,Cu^(2+)|Cu and Ag^(+)|Ag are respectively -0.76,0.34 and 0.8V . The following cells were constructed. Zn|Zn^(2+)"||"Cu^(2+)|Cu Zn|Zn^(2+)"||"Ag^(+)|Ag Cu|Cu^(2+)"||"Ag^(+)|Ag What is the correct order E_("cell")^(0) of these cell?

RESONANCE ENGLISH-ELECTROCHEMISRY-Part 2
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  14. Given the data at 25^(@)C, Ag((s)) +I((aq))^(-) rarr AgI((s)) +e^(-)...

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