Home
Class 12
CHEMISTRY
Given the data at 25^(@)C, Ag((s)) +I(...

Given the data at `25^(@)C`,
`Ag_((s)) +I_((aq))^(-) rarr AgI_((s)) +e^(-), E^(@) = 0.152V`
`Ag_((s)) rarr Ag_((aq))^(+) +e^(-), E^(@) =- 0.800V`
what is the value of log `K_(sp)` for `AgI`?
(Where `K_(sp)=` solubility product)
`(2.303(RT)/(F) =0.059V)`

A

`-8.12`

B

`+8.612`

C

`-37.83`

D

`-16.13`

Text Solution

Verified by Experts

The correct Answer is:
D

`0.152=-0.8-(0.059)/(1)logK_(SP):logK_(SP)=-16.11`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISRY

    RESONANCE ENGLISH|Exercise CBSE Problems|34 Videos
  • ELECTROCHEMISRY

    RESONANCE ENGLISH|Exercise Advanced Level Problems|88 Videos
  • ELECTROCHEMISRY

    RESONANCE ENGLISH|Exercise Exercise 3|7 Videos
  • ELECTRO CHEMISTRY

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (ELECTROCHEMISTRY)|53 Videos
  • EQUIVALENT CONCEPT & TITRATIONS

    RESONANCE ENGLISH|Exercise Part -IV|22 Videos

Similar Questions

Explore conceptually related problems

Given the data 25^(@) C , Ag+ I^(-) to AgI+e^(-) , E^(@) = 0.152V Ag to Ag^(+) + E(-) , E^(@) = - 0.800V What is the value of K_(sp) for AgI?

At 25^(@)C, {:(Ag+I^(-)rarr,AgI+e,,E^(@) =0.152V),(Agrarr,Ag.^(+)+e,,E^(@) =- 0.80V):} The log K_(sp) of AgI is: ((2.303RT)/(F)=0.059)

The standard oxidation potential of Zn and Ag in water at 20^(@) C" are: " Zn(s) rarr Azn^(2+) (aq) + 2e^(-) E^(o) = 0.76 V Ag(s) rarr Ag^(+)(aq) +e^(-) E^(o) = - 0.80 V Which one of the following reactions actually takes place?

Ag^(+) + e^(-) rarr Ag, E^(0) = + 0.8 V and Zn^(2+) + 2e^(-) rarr Zn, E^(0) = -076 V . Calculate the cell potential for the reaction, 2Ag + Zn^(2+) rarr Zn + 2Ag^(+)

At 20^(@) C, the standard oxidation potential of Zn and Ag in water are: Zn(s)rarr Zn^(2+) (aq) + 2e^(-), E^(o) = 0.76V , Ag(s) rarr Ag^(+)(aq) + E^(-) , E^(o) = - 0.80 V The standard EMF of the given reaction is: Zn+2Ag^(+)rarr 2AG+Zn^(+2)

Given that at 25^@C [Ag(NH_(3))_(2)]^(+) +e^(0) to Ag_((s))+2NH_(3) E^(0)=0.02V and Ag^(+)+1e^(-) to Ag_((s))" " E^(0)=0.8V Hence the order of magnitude of equilibrium constant of the reaction [Ag(NH_(3))_(2)]^(+) Leftrightarrow Ag^(+) +2NH_(3) , will be (antilog 0.22=1.66)

The half cell reactions with reduction potentials are Pb(s) to Pb^(+2) (aq), E_("red")^(@) =-0.13 V Ag(s) to Ag^(+) (aq) , E_("rod")^(@) =+0.80 V Calculate its emf.

Given : A^(2+)+2e^(-) rarr A(s)" "E^(c-)=0.08V B^(o+)+e^(-)rarr B(s)" "E^(c-)=-0.64V X_(2)(g)+2e^(-) rarr 2X^(c-)" "E^(c-)=1.03V Which of the following statements is // are correct ?

Based on the data given below, the correct order of reducing power is: Fe_((aq.))^(3+) + e rarr Fe_((aq.))^(2+), E^(@) = +0.77 V Al_((aq.))^(3+) + 3e rarr Al_((s)), E^(@) = -1.66 V Br_(2(aq.)) + 2e rarr 2Br_((aq.))^(-), E^(@) = +1.08 V

RESONANCE ENGLISH-ELECTROCHEMISRY-Part 2
  1. Conductance (Siemens, S) is directly proportional to the area of the v...

    Text Solution

    |

  2. At 25^(@)C, the standard emf of a cell having reaction involving two e...

    Text Solution

    |

  3. Standard reduction electrode potentials of three metals A,B and C are ...

    Text Solution

    |

  4. Consider the following E^@ values . E(Fe^(3+)//Fe^(2+)^@ = + 0.77 V, ...

    Text Solution

    |

  5. The limiting molar conductivities overset(o)(wedge) for NaCl, KBr an...

    Text Solution

    |

  6. In a cell that utilises the reaction ZN(s)+ 2H^(+)(aq)rightarrow Zn^(2...

    Text Solution

    |

  7. The E(M^(3+)//M^(2+))^(@) values for Cr, Mb, Fe and Co are -0.41, +1.5...

    Text Solution

    |

  8. The highest electrical conductivity of the following aqueous solution ...

    Text Solution

    |

  9. Aluminium oxide may be electrolysed at 1000^(@)C to furnish aluminium ...

    Text Solution

    |

  10. The molar conductivities, ^^(NaOAc)^(oo) and ^^(HCI)^(@) at infinite d...

    Text Solution

    |

  11. Given the data at 25^(@)C, Ag((s)) +I((aq))^(-) rarr AgI((s)) +e^(-)...

    Text Solution

    |

  12. Resistance of a conductivity cell filled with a solution of an electro...

    Text Solution

    |

  13. The equivalent conductances of two strong electrolytes at infinite dil...

    Text Solution

    |

  14. The cell : (Zn|Zn^(2+)(1M)|| Cu^(2+)(1M)|Cu) (E(cell)^(@)= 1.10V),wa...

    Text Solution

    |

  15. Given: E(Cr^(3+)//Cr)^(@) =- 0.72 V, E(Fe^(2+)//Fe)^(@) =- 0.42V. The ...

    Text Solution

    |

  16. Given : E(Fe^(3+)//Fe)^(@) = -0.036V, E(FE^(2+)//Fe)^(@)= -0.439V. The...

    Text Solution

    |

  17. The Gibbs energy for the decomposition of Al2O3 at 500^@C is as follow...

    Text Solution

    |

  18. The reduction potential of hydrogen half cell will be negative if :

    Text Solution

    |

  19. The standard reduction potentials for Zn^(2+)//Zn, Ni^(2+)//Ni, and Fe...

    Text Solution

    |

  20. Use the data given in Q.8 and find out which of the following is the ...

    Text Solution

    |