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How many of the following reactions are ...

How many of the following reactions are homogenous equilibrium reactions?
(1) `CH_(3)COOH(l)+C_(2)H_(5)OH(l)hArrCH_(3)COOC_(2)H_(5)(l)+H_(2)O(l)`
(2) `C(s)+CO_(2)(g)hArrCO(g)+H_(2)O(g)`
(3) `H_(2)(g)+CO_(2)(g)hArrCO(g)+H_(2)O(g)`
(4) `CO(g)+CI_(2)(g)hArrCOCI_(2)(g)`
(5) `NH_(4)HS_((s))hArrNH_(3)(g)+H_(2)S(g)`
(6) `CaCO_(3)(s)hArrCaO(s)+CO_(2)(s)`
(7) `N_(2)(g)+O_(2)(g)hArr2NO(g)`
(8) `CO_(2)(g)+C(s)hArr2CO(g)`
(9) `SO_(2)(g)+NO_(2)(g)hArrSO_(3)(g)+NO(g)`
(10) `NO(g)+(1)/(2)Br_(2)(l)hArr2NOBr(g)`

Text Solution

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The correct Answer is:
To determine how many of the given reactions are homogeneous equilibrium reactions, we need to analyze each reaction based on the definition of homogeneous equilibrium. A homogeneous equilibrium reaction is one where all reactants and products are in the same phase (all gases, all liquids, or all solids). Let's analyze each reaction step by step: 1. **Reaction 1: `CH₃COOH(l) + C₂H₅OH(l) ⇌ CH₃COOC₂H₅(l) + H₂O(l)`** - All reactants and products are in the liquid phase. - **Conclusion:** This is a homogeneous equilibrium reaction. (Yes) 2. **Reaction 2: `C(s) + CO₂(g) ⇌ CO(g) + H₂O(g)`** - Reactant is solid (C) and products are gases (CO and H₂O). - **Conclusion:** This is not a homogeneous equilibrium reaction. (No) 3. **Reaction 3: `H₂(g) + CO₂(g) ⇌ CO(g) + H₂O(g)`** - All reactants and products are in the gaseous phase. - **Conclusion:** This is a homogeneous equilibrium reaction. (Yes) 4. **Reaction 4: `CO(g) + Cl₂(g) ⇌ COCl₂(g)`** - All reactants and products are in the gaseous phase. - **Conclusion:** This is a homogeneous equilibrium reaction. (Yes) 5. **Reaction 5: `NH₄HS(s) ⇌ NH₃(g) + H₂S(g)`** - Reactant is solid (NH₄HS) and products are gases (NH₃ and H₂S). - **Conclusion:** This is not a homogeneous equilibrium reaction. (No) 6. **Reaction 6: `CaCO₃(s) ⇌ CaO(s) + CO₂(g)`** - Reactants are solid (CaCO₃, CaO) and product is gas (CO₂). - **Conclusion:** This is not a homogeneous equilibrium reaction. (No) 7. **Reaction 7: `N₂(g) + O₂(g) ⇌ 2NO(g)`** - All reactants and products are in the gaseous phase. - **Conclusion:** This is a homogeneous equilibrium reaction. (Yes) 8. **Reaction 8: `CO₂(g) + C(s) ⇌ 2CO(g)`** - Reactant is gas (CO₂) and product is solid (C) and gas (CO). - **Conclusion:** This is not a homogeneous equilibrium reaction. (No) 9. **Reaction 9: `SO₂(g) + NO₂(g) ⇌ SO₃(g) + NO(g)`** - All reactants and products are in the gaseous phase. - **Conclusion:** This is a homogeneous equilibrium reaction. (Yes) 10. **Reaction 10: `NO(g) + (1/2)Br₂(l) ⇌ 2NOBr(g)`** - Reactant is liquid (Br₂) and products are gases (NOBr). - **Conclusion:** This is not a homogeneous equilibrium reaction. (No) Now, let's summarize the results: - Homogeneous equilibrium reactions: 1, 3, 4, 7, 9 - Total homogeneous equilibrium reactions = 5 **Final Answer:** There are 5 homogeneous equilibrium reactions.
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