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X overset(Sn//HCl) to overset(NaNO(2))un...

`X overset(Sn//HCl) to overset(NaNO_(2))underset(HCl)to Z overset(CuCN)underset(Delta)to (P) overset(H_(3)O)to Ph-COOH` correct options is/are:

A

X is Ph`-NH_(2)`

B

Y is `Ph-NO_(2)`

C

Z is `Ph-NH_(2)`

D

P is Ph-CN

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the transformations occurring from compound X to the final product Ph-COOH. ### Step 1: Identify Compound X The first reagent is Sn/HCl, which is a reducing agent. It is used to reduce nitro groups (NO2) to amine groups (NH2). Therefore, we can conclude that: - **X = Ph-NO2 (Nitrobenzene)** ### Step 2: Reduction of X to Y When X (Ph-NO2) is treated with Sn/HCl, it is reduced to an amine: - **Y = Ph-NH2 (Aniline)** ### Step 3: Diazotization of Y to Z Next, Y is treated with NaNO2 in HCl. This reaction is known as diazotization, where an amine is converted to a diazonium salt: - **Z = Ph-N2^+ Cl^- (Benzene diazonium chloride)** ### Step 4: Reaction of Z with CuCN to form P The diazonium salt Z is then treated with CuCN, which introduces a cyanide group (CN) to the aromatic ring: - **P = Ph-C≡N (Benzene cyanide)** ### Step 5: Hydrolysis of P to form the final product The final step involves the hydrolysis of P (Ph-C≡N) using H3O^+. This reaction converts the nitrile group (C≡N) into a carboxylic acid (COOH): - **Final Product = Ph-COOH (Benzoic acid)** ### Summary of the transformations: - **X = Ph-NO2** - **Y = Ph-NH2** - **Z = Ph-N2^+ Cl^-** - **P = Ph-C≡N** - **Final Product = Ph-COOH** ### Correct Option From the analysis, we can conclude that the only correct statement is: - P is Ph-C≡N, which is correct.

To solve the problem step by step, we will analyze the transformations occurring from compound X to the final product Ph-COOH. ### Step 1: Identify Compound X The first reagent is Sn/HCl, which is a reducing agent. It is used to reduce nitro groups (NO2) to amine groups (NH2). Therefore, we can conclude that: - **X = Ph-NO2 (Nitrobenzene)** ### Step 2: Reduction of X to Y When X (Ph-NO2) is treated with Sn/HCl, it is reduced to an amine: ...
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