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Which of the following is incorrect:...

Which of the following is incorrect:

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the options is incorrect, we will analyze each option provided in the question step by step. ### Step 1: Analyze Option A - **Statement**: Phenol with chloroform and potassium hydroxide undergoes a reaction known as the Drymer-Trimon reaction. - **Explanation**: In this reaction, phenol reacts with chloroform in the presence of a strong base (potassium hydroxide) to form ortho and para-substituted products. The para product is generally the major product. - **Conclusion**: This statement is correct. ### Step 2: Analyze Option B - **Statement**: Aniline on treatment with chloroform and potassium hydroxide undergoes the carbylamine reaction, resulting in the formation of isocyanide. - **Explanation**: The carbylamine reaction involves the reaction of primary amines (like aniline) with chloroform and a strong base (KOH) to produce isocyanides. - **Conclusion**: This statement is also correct. ### Step 3: Analyze Option C - **Statement**: Aniline with chloroform and KOH produces isocyanides. - **Explanation**: This statement appears to be a repetition of the carbylamine reaction mentioned in Option B. However, if it implies that aniline does not produce isocyanides when treated with chloroform and KOH, then it is incorrect. - **Conclusion**: This statement is incorrect. ### Step 4: Analyze Option D - **Statement**: Phenol in the presence of carbon dioxide and a base gives salicylic acid. - **Explanation**: This reaction is known as the Kolbe's electrolysis or the carboxylation of phenol, where phenol reacts with carbon dioxide in the presence of a base to form salicylic acid. However, if the statement implies that this reaction can occur without carbon dioxide, it is incorrect. - **Conclusion**: This statement is also incorrect. ### Final Conclusion The incorrect options are C and D.

To determine which of the options is incorrect, we will analyze each option provided in the question step by step. ### Step 1: Analyze Option A - **Statement**: Phenol with chloroform and potassium hydroxide undergoes a reaction known as the Drymer-Trimon reaction. - **Explanation**: In this reaction, phenol reacts with chloroform in the presence of a strong base (potassium hydroxide) to form ortho and para-substituted products. The para product is generally the major product. - **Conclusion**: This statement is correct. ### Step 2: Analyze Option B ...
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